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HIPed Tailored Pyrochlore-Rich Glass-Ceramic Waste Forms for the Immobilization of Nuclear Waste

Published online by Cambridge University Press:  01 February 2011

Melody Lyn Carter ,
Hui Li ,
Yingjie Zhang ,
Andrew L Gillen  and
Eric R Vance
Melody Lyn Carter
Affiliation:
[email protected], ANSTO, Lucas Heights, New South Wales, Australia
Hui Li
Affiliation:
[email protected], ANSTO, Lucas Heights, New South Wales, Australia
Yingjie Zhang
Affiliation:
[email protected], ANSTO, Lucas Heights, New South Wales, Australia
Andrew L Gillen
Affiliation:
[email protected], ANSTO, Lucas Heights, New South Wales, Australia
Eric R Vance
Affiliation:
[email protected], ANSTO, Lucas Heights, New South Wales, Australia
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Abstract

Hot isostatically pressed (HIPed) glass-ceramics for the immobilization of uranium-rich intermediate-level wastes and Hanford K-basin sludges were designed. These were based on pyrochlore-structured Ca(1-x)U(1+y)Ti2O7 in glass, together with minor crystalline phases. Detailed microstructural, diffraction and spectroscopic characterization of selected glass-ceramic samples has been performed, and chemical durability is adequate, as measured by both MCC-1 and PCT-B leach tests.

Keywords

nuclear materialshot isostatic pressing (HIP)U
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1124: Symposium Q – Scientific Basis for Nuclear Waste Management XXXII , 2008 , 1124-Q04-01
Copyright
Copyright © Materials Research Society 2009

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References

REFERENCES

1. Loiseau, P., Caurant, D., Baffier, N. and Fillet, C., in Scientific Basis for Nuclear Waste Management XXIV edited by Hart, K. P. and Lumpkin, G. R. (Mater. Res. Soc. Symp. Proc. 663, Pittsburgh, PA, 2002) pp. 169–177.Google Scholar
2. Zhao, D., Li, L., Davis, L. L., Weber, W. J. and Ewing, R. C., in Scientific Basis for Nuclear Waste Management XXIV edited by Hart, K. P. and Lumpkin, G. R. (Mater. Res. Soc. Symp. Proc. 663, Pittsburgh, PA, 2002) pp. 199–206.Google Scholar
3. Loiseau, P., Caurant, D., Majerus, O., Baffier, N. and Fillet, C., J. Mater. Sci. 38 (4), 843–852 (2003).Google Scholar
4. Loiseau, P., Caurant, D., Majerus, O., Baffier, N. and Fillet, C., in Scientific Basis for Nuclear Waste Management XXVII edited by Oversby, V. M. and Werme, L. O., (Mater.Res. Soc. Symp. Proc. 807, Pittsburgh, PA, 2004) pp 333–338.Google Scholar
5. Loiseau, P., Caurant, D., Mazerolles, L., Baffier, N. and Fillet, C., J. Nucl. Mater. 335, 14–32 (2004).Google Scholar
6. Caurant, D., Majerus, O., Loiseau, P., Bardez, I., Baffier, N. and Dussossoy, J. L., J. Nucl. Mater. 354 (1–3), 143–162 (2006).Google Scholar
7. Day, R.A., Ferenzy, J., Drabarek, E., Advocat, T., Fillet, C., Lacombe, J., Ladirat, C., Veyer, C., Do Quang, R. and Thomasson, J., WM'03 Conference, February 23–27, 2003, Tucson, AZ on CD.Google Scholar
8. Digeos, A.A., Valdez, J.A., Sickafus, K.E., Atiq, S., Grimes, R.W. and Boccaccini, A.R., J. Mater. Sci. 38 (2003) 1597–1604.Google Scholar
9. Boccaccini, A.R., Bernardo, E., Blain, I. and Boccaccini, N.D., J. Nucl. Mater. 327, 148–158 (2004).Google Scholar
10. Vance, E. R., Hayward, P. J., Cann, C. D., Mitchell, S. L., Stanchell, M. A. T. and Wren, D. J., Glass Technology 25 (5), 232–239 (1984).Google Scholar
11. Vance, E.R., Urquhart, S., Anderson, D. and George, I.M., in Advances in Ceramics, Vol. 20 edited by Clark, D.E., White, W.B. and Machiels, A-J., (American Ceramics Society, Westerville, OH, U.S.A. 1987), pp. 249–258.Google Scholar
12. Rittmann, P. D., Report No.SNF-5066, Rev. 0, 1999.Google Scholar
13. Wendlandt, W. W. and Hecht, H. G., Reflectance Spectroscopy, Wiley Interscience, New York, 1966.Google Scholar
14. PCT is based on the ASTM Designation: C 1285–02 Standard Test Methods for Determining Chemical Durability of Nuclear, Hazardous, and Mixed Waste Glasses and Multiphase Glass Ceramics: The Product Consistency Test (PCT). (2002)Google Scholar
15. ASTM C 1220 – 98. “Standard Test Method for Static Leaching of Monolithic Waste Forms for Disposal of Radioactive Waste”. ASTM International. (1998).Google Scholar
16. Stewart, M. W. A., Vance, E. R., Jostsons, A., and Ebbinghaus, B. B., Journal of the Australasian Ceramic Society, 39 (2) 130–148 (2003).Google Scholar
17. Zhang, Y., Hart, K. P., Blackford, M. G., Thomas, B. S., Aly, Z., Lumpkin, G. R., Stewart, M. W., McGlinn, P. J., and Brownscombe, A., in Scientific Basis for Nuclear Waste Management XXIV edited by Hart, K. P. and Lumpkin, G. R. (Mater.Res. Soc. Symp. Proc. 663, Pittsburgh, PA, 2002) pp. 325–332.Google Scholar
18. James, M., Carter, M.L., Zhang, Y., Zhang, Z. and Vance, E.R. To be published.Google Scholar
19. Zhang, Y., Vance, E. R., Finnie, K. S., Begg, B. D. and Carter, M. L., Royal Society of Chemistry, (2006) 343–345.Google Scholar
20. Zhang, Y., Li, H., McGlinn, P.J., Yang, B. and Begg, B.D., J. Nucl. Mater. 375 (3), 315–322 (2008).Google Scholar