Hostname: page-component-7bb8b95d7b-lvwk9 Total loading time: 0 Render date: 2024-10-03T04:28:29.024Z Has data issue: false hasContentIssue false
  • English
  • Français

A Study of Diffusion of Li+ in the [NZP] Network

Published online by Cambridge University Press:  10 February 2011

G. Bhuvaneswari  and
U.V. Varadaraju
G. Bhuvaneswari
Affiliation:
Materials Science Research CentreIndian Institute of Technology, Madras-36, India
U.V. Varadaraju
Affiliation:
Materials Science Research CentreIndian Institute of Technology, Madras-36, India
Get access

Abstract

Li+ has been incorporated in the 3D -framework of PbM3+M4+P3O12 by soft chemistry method using n-butyl lithium at RT. It is shown that the framework of the [NZP] structure remains intact upon Li+ insertion and provides a three dimensional interstitial pathway for Li+ ion diffusion.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 527: Symposium Z – Diffusion Mechanisms in Crystalline Materials , 1998 , 513
Copyright
Copyright © Materials Research Society 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Hagman, L. and Kierkegaard, P., Acta.chem.Scand. 22, 1822 (1968).Google Scholar
2. Leclaire, A., Borel, M.M., Grandin, A. and Raveau, B., Actacrystallogr.Sect. C45, 699 (1989).Google Scholar
3. Sugantha, M., Ph.D. Thesis, IIT Madras (1996).Google Scholar
4. Rietveld, H.M., Acta Crystallogr. 2 65 (1969).Google Scholar
5. Kohler, H. and Schulz, H., Mater.Res.Bull, 20,1461 (1985).Google Scholar