Published online by Cambridge University Press: 21 February 2011
The structural and electrical properties of heteroepitaxial HgCdTe/CdZnTe/GaAs/Si were evaluated using high-resolution x-ray diffraction techniques and Hall-effect measurements as a function of temperature. Significant tilting of the layers was found for both {100} and {111} CdZnTe layers grown on misoriented {100}GaAs/Si substrates, consistent with the interpretation of a low-angle tilt boundary being formed at the interface to relieve the large lattice mismatch between the layers. The GaAs layer is in a state of biaxial tension before and after the growth of the CdZnTe layers. The x-ray FWHM of HgCdTe layers grown by LPE on these substrates was found to be reduced from that of the MOCVD-grown CdZnTe buffer layer due to both an annealing effect during LPE growth and to the increased distance of layer surface from the defective CdZnTe/GaAs interface. Hall-effect mobility for {100}HgCdTe layers was nearly identical to that of layers grown on bulk CdZnTe substrates. High-quality heterojunction infrared detectors have been fabricated using these materials.