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Real-Time Kinetic Analysis of Hydrogen Abstraction and Etching Reactions Using Pulsed-Gas PECVD of Amorphous and Microcrystalline Silicon

Published online by Cambridge University Press:  15 February 2011

Easwar Srinivasan
Affiliation:
Department of Chemical Engineering, N.C. State University, Raleigh, NC 27695
Gregory N. Parsons
Affiliation:
Department of Chemical Engineering, N.C. State University, Raleigh, NC 27695
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Abstract

Hydrogen elimination reactions, abstraction and etching, are monitored in real-time using a differentially pumped mass spectrometer, while intermittently exposing a hydrogenated silicon surface to atomic deuterium. The mass spectrometer signals are used to predict the kinetics of the abstraction reaction, and to qualitatively treat the etch reaction.

Type
Research Article
Copyright
Copyright © Materials Research Society 1997

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