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Radiation Stability of Crown Ether Used for Decontamination of Radionuclides from HLW

Published online by Cambridge University Press:  03 September 2012

Vyacheslav M. Abashkin
Affiliation:
Russian Research Institute of Chemical Technology, 33 Kashirskoe Ave., Moscow 115230, [email protected]
Gennadiy F. Egorov
Affiliation:
Russian Research Institute of Chemical Technology, 33 Kashirskoe Ave., Moscow 115230, [email protected]
Evgeniy Filippov
Affiliation:
Russian Research Institute of Chemical Technology, 33 Kashirskoe Ave., Moscow 115230, [email protected]
Anna K. Nardova
Affiliation:
Russian Research Institute of Chemical Technology, 33 Kashirskoe Ave., Moscow 115230, [email protected]
Igor V. Mamakin
Affiliation:
Russian Research Institute of Chemical Technology, 33 Kashirskoe Ave., Moscow 115230, [email protected]
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Abstract

The gamma-ray initiated oxidation of dicyclohexano-18-crown-6 (DCH-6) was studied in two-phase system under agitation: nitric acid, aqueous solution and organic solvent.

The distribution coefficients of radionuclides, hydrodynamic characteristics (phase separation and interface surface tension), and the radiolysis products after irradiation at a dose rate (60Co) of 1.7 Gy/s were determined. The maximum total dose was 3.O×105 Gy (3.0×107R).

Type
Research Article
Copyright
Copyright © Materials Research Society 1997

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References

REFERENCES

1. Melson, G.A., Coordination Chemistry of Macrocvclic Compounds, Plenum Press, New York and London, 1979.Google Scholar
2. Egorov, G.V., Radiochemistry of Solvent Extraction Systems Energoizdat, Moscow, 1986.Google Scholar
3. Horwitz, E.P., Dietz, M.L., and Fisher, D.E., SREX: A new process for the extraction and recovery of Strontium from acidic nuclear waste streams. Solvent Extr. Ion Exck, 8, 199 (1990).Google Scholar
4. Filippov, Y. A., Dzekun, E.A., Nardov, A.K. et al. (1992) Application of crown ethers and ferrocvanide based inorganic material for cesium and strontium recovery. In Proceedings of the Annual Symposium on Waste Management at Tucson AZ, 2, 1021 (1992).Google Scholar
5. Pyatnitski, I.V. Chemistry and Technology of Water (Rus.). Naukova Dumka: Kiev, 1983, 5, P.224.Google Scholar