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Nanometer-scale Structural Relaxation in Zr-based Bulk Metallic Glass

Published online by Cambridge University Press:  01 February 2011

Jinwoo Hwang
Affiliation:
[email protected], University of Wisconsin-Madison, Materials Science and Engineeing, #202, 1509 University ave, Madison, WI, 53706, United States
Hongbo Cao
Affiliation:
[email protected], University of Wisconsin, Madison, Materials Science and Engineering, Madison, WI, 53706, United States
Paul M. Voyles
Affiliation:
[email protected], University of Wisconsin, Madison, Materials Science and Engineering, Madison, WI, 53706, United States
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Abstract

We investigated the influence of annealing on the nanometer-scale medium-range order in Zr54Cu38Al8 bulk metallic glass using fluctuation electron microscopy. Fluctuation microscopy experiments probing structure at a length scale of 1 nm show that the as-cast Zr bulk metallic glass contains significant medium range order. That structure is unchanged by annealing at 87% of the glass transition temperature for 24 hours, although that anneal does significantly change the differential scanning calorimetry trace.

Type
Research Article
Copyright
Copyright © Materials Research Society 2008

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