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Design of Π-conjugated Graft and Block Copolymers: A Tool Box for Nanostructured Materials in Optoelectronic Devices

Published online by Cambridge University Press:  04 September 2012

Cyril Brochon ,
Sebastien-Jun Mougnier ,
Eric Cloutet  and
Georges Hadziioannou
Cyril Brochon
Affiliation:
Université de Bordeaux, Laboratoire de Chimie des Polymères Organiques (LCPO), UMR 5629, IPB-ENSCBP 16 avenue Pey-Berland, 33607 Pessac Cedex, France
Sebastien-Jun Mougnier
Affiliation:
Université de Bordeaux, Laboratoire de Chimie des Polymères Organiques (LCPO), UMR 5629, IPB-ENSCBP 16 avenue Pey-Berland, 33607 Pessac Cedex, France
Eric Cloutet
Affiliation:
Université de Bordeaux, Laboratoire de Chimie des Polymères Organiques (LCPO), UMR 5629, IPB-ENSCBP 16 avenue Pey-Berland, 33607 Pessac Cedex, France
Georges Hadziioannou
Affiliation:
Université de Bordeaux, Laboratoire de Chimie des Polymères Organiques (LCPO), UMR 5629, IPB-ENSCBP 16 avenue Pey-Berland, 33607 Pessac Cedex, France
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Abstract

Semi-conducting conjugated (co)polymers are well soluble and can be processed easily in a large scale. Among these materials, rod-coil block and graft copolymers, show very particular properties of self-assembly, and are very promising in organic electronic, as organic photovoltaic materials for example.

The post-functionalization of poly(3-hexylthiophene) (P3HT) from ω-allyl terminated P3HT via various synthetic routes is reported in order to obtain well-defined block and graft copolymers for optoelectronic or photovoltaic applications. First, a well-defined and monofunctional P3HT-based macro-initiator has been obtained through a clean and versatile process. Well-defined rod-coil block copolymers were obtained by nitroxide mediated radical polymerization (NMRP) with various monomers. Finally, three different novel P3HT-based graft copolymers were synthesized following two routes.

Keywords

polymerizationorganicphotovoltaic
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1448: Symposium Z – Conjugated Organic Materials for Energy Conversion, Energy Storage and Charge Transport , 2012 , mrss12-1448-z11-04
Copyright
Copyright © Materials Research Society 2012

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References

REFERENCES

1. Schmidt-Mende, L.; Fechtenkötter, A.; Müllen, K.; Moons, E.; Friend, R. H.; MacKenzie, J. D. Science 2001, 293, 1119–1122.Google Scholar
2. Granstrom, M.; Petritsch, K.; Arias, A. C.; Lux, A.; Andersson, M. R.; Friend, R. H. Nature 1998, 395, 257–260.Google Scholar
3. Coakley, K. M.; McGehee, M. D. Chemistry of Materials 2004, 16, 4533–4542 Google Scholar
4. Jen, K.-Y., Miller, G. G., Elsenbaumer, R. L., Chemical Communications 1986, 1346.Google Scholar
5. McCullough, R. D., Lowe, R. D., Chemical Communications 1992, 70.Google Scholar
6. Miyakoshi, R., Yokoyama, A., Yokozawa, T., Journal of the American Chemical Society 2005, 127, 17542.Google Scholar
7. Sheina, E. E., Liu, J., Iovu, M. C., Laird, D. W., McCullough, R. D., Macromolecules 2004, 37, 3526.Google Scholar
8. Stefan, M. C., Javier, A. E., Osaka, I., McCullough, R. D., Macromolecules 2008, 42, 30.Google Scholar
9. Richard, F., Brochon, C., Leclerc, N., Eckhardt, D., Heiser, T., Hadziioannou, G., Macromolecular Rapid Communications 2008, 29, 885.Google Scholar
10. Iovu, M. C., Jeffries-El, M., Sheina, E. E., Cooper, J. R., McCullough, R. D., Polymer 2005, 46, 8582.Google Scholar
11. Iovu, M. C., Craley, C. R., Jeffries-El, M., Krankowski, A. B., Zhang, R., Kowalewski, T., McCullough, R. D., Macromolecules 2007, 40, 4733.Google Scholar
12. Iovu, M. C., Zhang, R., Cooper, J. R., Smilgies, D. M., Javier, A. E., Sheina, E. E., Kowalewski, T., McCullough, R. D., Macromolecular Rapid Communications 2007, 28, 1816.Google Scholar
13. Urien, M., Erothu, H., Cloutet, E., Hiorns, R. C., Vignau, L., Cramail, H., Macromolecules 2008, 41, 7033.Google Scholar
14. de Cuendias, A, Hiorns, R. C., Cloutet, E., Vignau, L., Cramail, H., Polymer International 2010, 59, 1452.Google Scholar
15. Chevalier, Y., Current Opinion in Colloid & Interface Science 2002, 7, 3.Google Scholar
16. Jeffries-EL, M., Sauvé, G., McCullough, R. D., Advanced Materials 2004, 16, 1017.Google Scholar
17. Jeffries-El, M., Sauve, G., McCullough, R. D., Macromolecules 2005, 38, 10346.Google Scholar
18. Mougnier, S.-J., Brochon, C., Cloutet, E., Fleury, G., Cramail, H., Hadziioannou, G., Macromolecular Rapid Communications (2012) Accepted DOI#10.1002/marc 201100703 Google Scholar
19. Mougnier, S.-J., Brochon, C., Cloutet, E., Magnet, S., Navarro, C. and Hadziioannou, G., JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY (2012) accepted DOI# 10.1002/POLA 26023 Google Scholar
20. Renaud, C., Mougnier, S.-J., Pavlopoulou, E., Brochon, C., Deribew, D., Cloutet, E., Chambon, S., Vignau, L., Hadziioannou, G., Advanced Materials (2012) accepted DOI# 10.1002/adma 201104461 Google Scholar