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Plutonium Oxide Systems and Related Corrosion Products

Published online by Cambridge University Press:  31 January 2011

R.G. Haire  and
J.M. Haschke
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Extract

Elemental plutonium is considered to be one of the most complex elements in the periodic table and, by some, one of the more toxic, given its moderate radioactivity and that it is a heavy metal. Essentially a manuf actured element (only traces are found in nature), it was first discovered and produced some six decades ago. Amazingly, hundreds of tons of plutonium are pre sently in existence. Crystalline solids formed by plutonium and nonmetallic elements (e.g., hydrogen, oxygen, halides, etc.) were some of the first compounds investigated, and oxides and oxide-related materials have always been important compounds.

Type
Research Article
Information
MRS Bulletin , Volume 26 , Issue 9: Challenges in Plutonium and Actinide Materials Science , September 2001 , pp. 689 - 696
Copyright
Copyright © Materials Research Society 2001

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References

1. “Safe Handling and Storage of Plutonium,” Technical Report Series, No. 9 (International Atomic Energy Agency, Vienna, 1998).Google Scholar
2.George, T.G. and Foltyn, E.M., AIP Conf. (CONF-980103), January 1998.Google Scholar
3.Rinehart, G.H., AIP Conf. (CONF-970115), January 1997.Google Scholar
4.Weigel, F., Katz, J.J., and Seaborg, G.T., in Chemistry of the Actinide Elements, Vol. 1, edited by Katz, J.J., Seaborg, G.T., and Morss, L.R. (Chapman & Hall, London, 1986).Google Scholar
5. “Plutonium Futures–The Science” Conf. Trans., APS Conf. Proc. 532, Santa Fe, NM, July10–13, 2000.Google Scholar
6.Domanov, V.P., Buklanov, G.V., and Lobanov, Yu.V., presented at the 5th Int. Conf. on Nuclear and Radiochemistry, Pontresina, Switzerland, September 2000.Google Scholar
7.Ronchi, C., Capone, F., Colle, J.Y., and Hiernaut, J.P., J.Nucl. Mater. 280 (2000) p.111.CrossRefGoogle Scholar
8.Haschke, J.M., Allen, T.H., and Morales, L.A., in Los Alamos Science, Vol. 26, edited by Cooper, N.G. (Los Alamos National Laboratory, Los Alamos, NM, 2000).Google Scholar
9.Wick, O.J., Plutonium Handbook, Chap. 8 (American Nuclear Society, La Grange Park, IL, 1980).Google Scholar
10.Cleveland, J.M., The Chemistry of Plutonium (Gordon & Breach Science Publishers, New York, 1970).Google Scholar
11.Colmenares, C.A., Prog. Solid State Chem. 9 (1975) p.139.CrossRefGoogle Scholar
12.Colmenares, C.A., Prog. Solid State Chem. 15 (1984) p.257.CrossRefGoogle Scholar
13.Wriedt, H.A., Bull. Alloy Phase Diagr. 11 (2) (1990) p.184.CrossRefGoogle Scholar
14.Morss, L.R., in Chemistry of the Actinide Elements, Vol. 1, edited by Katz, J.J., Seaborg, G.T., and Morss, L.R. (Chapman & Hall, London, 1986).Google Scholar
15.Holley, C.S. Jr, Mulford, R.N.R., Huber, E.J. Jr, Head, E.L., Ellinger, F.H., and Bjork-lund, C.W., in Proc. 2nd Int. Conf. on Peaceful Uses of Atomic Energy, Vol. 6 (United Nations, Geneva, 1958) p.215.Google Scholar
16.Brewer, L., Chem. Rev. 52 (1953) p.1.CrossRefGoogle Scholar
17.Gardner, E.R., Markin, T.L., and Street, R.S., J.Inorg. Nucl. Chem. 27 (1965) p.541.CrossRefGoogle Scholar
18.Eyring, L., in Handbook on the Physics and Chemistry of Rare Earths, Vol. 3, edited by Gschneidner, K.A. Jr. and Eyring, L. (North-Holland, Amsterdam, 1979).Google Scholar
19.Haire, R.G. and Eyring, L., in Handbook on the Physics and Chemistry of Rare Earths, Vol. 18, edited by Gschneidner, K.A. Jr, Eyring, L., Choppin, G.R., and Lander, G.H. (North-Holland, New York, 1994) p.413.Google Scholar
20.Ackermann, R.J., Faircloth, R.L., and Rand, M.H., J.Phys. Chem. 70 (1966) p.3698.CrossRefGoogle Scholar
21.Terada, K., Meisel, R.L., and Dringman, M.R., J.Nucl. Mater. 30 (1969) p.340.CrossRefGoogle Scholar
22.Haschke, J.M., Hodges, A.E. III, Bixby, G.E., and Lucas, R.L., Report R-FP-3416 (Rockwell International, Rocky Flats Plant, Golden, CO, February 1983).Google Scholar
23.Haschke, J.M., in Transuranium Elements: A Half Century, Chap. 40, edited by Morss, L.R. and Fuger, J. (American Chemical Society, Washington, DC, 1992) p.417.Google Scholar
24.Rai, D. and Sterne, R.J., J. Environ. Qual. 6 (1977) p.89.CrossRefGoogle Scholar
25.Allard, B., Oloffson, U., and Torstenfelt, B., Inorg. Chim. Acta 94 (1984) p.205.CrossRefGoogle Scholar
26.Waber, J.T., in Plutonium Handbook, Chap. 6, edited by Wick, O.J. (American Nuclear Society, La Grange Park, IL, 1980).Google Scholar
27.Haire, R.G., Lloyd, M.H., Beasley, M.H., and Milligan, W.O., J.Electron Microsc. 20 (1971) p.8.Google Scholar
28.Lloyd, M.H. and Haire, R.G., Radiochim. Acta 25 (1978) p.139.CrossRefGoogle Scholar
29.Conradson, S.D., Appl. Spectrosc. 52 (1998) p.225A.CrossRefGoogle Scholar
30.Bagnall, K.W. and Laidler, J.B., J. Chem. Soc. 86 (1964) p.2693.CrossRefGoogle Scholar
31.Cleveland, J.M., J. Inorg. Nucl. Chem. 26 (1964) p.461.CrossRefGoogle Scholar
32.Knopp, R., Neck, V., and Kim, J.I., Radiochim. Acta 86 (1999) p.101.CrossRefGoogle Scholar
33.Gibson, J.K. and Haire, R.G., J.Alloys Compd. 322 (2001) p.143.CrossRefGoogle Scholar
34.Domanov, V.p., Buklanov, G.V., and Lobanov, Yu.V. (private communication).Google Scholar
35.Santos, M., Marcalo, J., Matos, A.p. de, Gibson, J.K., and Haire, R.G., to be presented at the 6thEur. Workshop on Fourier Transform Ion Cyclotron Mass Spectrometry, Kerkrade, The Netherlands, October 16–19, 2001.Google Scholar
36.Haschke, J.M., Allen, T.H., and Morales, L.A., Science 5451 (2000) p.285.CrossRefGoogle Scholar
37.Marquart, R., Hoffman, G., and Weigel, F., J.Less-Common Met. 91 (1983) p.199.CrossRefGoogle Scholar
38.Stakebake, J.L., Larson, D.T., and Haschke, J.M., J.Alloys Compd. 202 (1993) p.251.CrossRefGoogle Scholar
39.Haschke, J.M. and Allen, T.H., Report LA-13537-MS (Los Alamos National Laboratory, Los Alamos, NM, January 1999).Google Scholar
40.Morales, L.A., Clark, D.L., Allen, T.H., and Haschke, J.M., Formation and Involvement of PuO2+x in the Dissolution Rate of Environmen-tal Plutonium Oxide, Report UCRL-ID-135626 (Lawrence Livermore National Laboratory, Livermore, CA); L.A. Morales, D.I. Clark, T.H. Allen, and J.M. Haschke, presented at the Seventh International Conference on the Chemistry and Migration Behavior of Actinides and Fission Products in the Geosphere, Lake Tahoe, NV, September 1999.Google Scholar
41.Raison, P.E., Haire, R.G., Sato, T., and Ogawa, T., in Scientific Basis for Nuclear Waste Management XXII, edited by Wronkiewicz, D.J. and Lee, J.H. (Mater. Res. Soc. Symp. Proc. 556, Warrendale, PA, 1999), p.3.Google Scholar
42.Flotow, H.E., Osborne, D.W., Fried, S.M., and Malm, J.G., J.Chem. Phys. 65 (1976) p.1124.CrossRefGoogle Scholar
43.Nelson, L.S., High Temp. Sci. 12 (1980) p.297.Google Scholar
44.Martz, J.C. and Haschke, J.M., J.Alloys Compd. 266 (1998) p.90.CrossRefGoogle Scholar
45.Haschke, J.M. and Allen, T.M., J.Alloys Compd. 320 (2001) p.58.CrossRefGoogle Scholar
46.Stakebake, J.L., J.Nucl. Mater. 38 (1971) p.241.CrossRefGoogle Scholar
47.Stakebake, J.L., in Transuranium Elements: A Half Century, Chap. 27, edited by Morss, L.R. and Fuger, J. (American Chemical Society, Washington, DC, 1992) p.251.Google Scholar
48.Stakebake, J.L. and Steward, L.M., J. Electro-chem. Soc. 119 (1972) p.730.CrossRefGoogle Scholar
49.Stakebake, J.L., J.Less-Common Met. 123 (1986) p.185.CrossRefGoogle Scholar
50.Stakebake, J.L. and Lewis, L.A., J.Nucl. Mater. 148 (1987) p.115.CrossRefGoogle Scholar
51.Stakebake, J.L. and Lewis, L.A., J.Less-Common Met. 136 (1988) p.349.CrossRefGoogle Scholar
52.Stakebake, J.L. and Saba, M.A., J.Less-Common Met. 158 (1990) p.221.CrossRefGoogle Scholar
53.Haschke, J.M., Allen, T.H., and Morales, L.A., J.Alloys Compd. 314 (2001) p.78.CrossRefGoogle Scholar
54.Flotow, H.E., Haschke, J.M., and Yamauchi, S., in The Chemical Thermodynamics of Actinide Elements and Compounds, Part 9, edited by Oetting, F.L. (International Atomic Energy Agency, Vienna, 1984).Google Scholar
55.Haschke, J.M., Allen, T.H., and Stakebake, J.L., J.Alloys Compd. 243 (1996) p.23.CrossRefGoogle Scholar
56.Martz, J.C., Haschke, J.M., and Stakebake, J.L., J.Nucl. Mater. 210 (1994) p.130.CrossRefGoogle Scholar
57.Haschke, J.M. and Martz, J.C., in Encyclopedia of Environmental Analysis and Remediation, Vol.6, edited by Meyers, R.A. (John Wiley & Sons, New York, 1998) p.3740; J.M. Haschke, T. Allen, and J. Martz, J. Alloys Compd. 271/273 (1998) p.211.Google Scholar