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Infrared reflectance of single-crystal jarandolite, CaB3O4(OH)3

Published online by Cambridge University Press:  05 July 2018

P. M. Nikolić*
Affiliation:
Institute of Technical Science of SASA, Knez Mihailova 35/IV, P.Box 315, 11000 Belgrade, Serbia
S. Đurić
Affiliation:
Institute of Technical Science of SASA, Knez Mihailova 35/IV, P.Box 315, 11000 Belgrade, Serbia
K. M. Paraskevopoulos
Affiliation:
Physics Department, Solid State Section, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece
T. T. Zorba
Affiliation:
Physics Department, Solid State Section, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece
D. Luković
Affiliation:
Institute of Technical Science of SASA, Knez Mihailova 35/IV, P.Box 315, 11000 Belgrade, Serbia
S. Savić
Affiliation:
Institute of Technical Science of SASA, Knez Mihailova 35/IV, P.Box 315, 11000 Belgrade, Serbia
V. Blagojević
Affiliation:
Faculty of Electronic Engineering, University of Belgrade, Bulevar Kralja Aleksandra 73, 11000 Belgrade, Serbia
M. V. Nikolić
Affiliation:
Centre for Multidisciplinary Studies of the University of Belgrade, Kneza Viseslava 1, 11000 Belgrade, Serbia
*

Abstract

Polarized far- and mid-infrared reflectance spectra were measured at room temperature for the new mineral species jarandolite, CaB3O4(OH)3, for the two principal directions. Thirty three vibration modes for and 32 for were observed and analysed numerically. Symmetry analysis predicts 41 and 40 vibration modes that include lattice and O–H modes. Mode assignment was made based on the structure of jarandolite. The values of the mode frequencies (ωTO), the damping factors (γ) and the oscillator strength (S) of each oscillator were obtained by fitting to a Lorentz model.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2007

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References

Adams, D. and Newton, D. (1970) Tables for factor group and point group analysis. Beckman, RIIC, Crayden, UK.Google Scholar
Bhagavantam, S. and Venkatarayudu, T. (1951) Theory of Groups and its Application to Physical Problems, 2nd edition. Bangalore Press, Bangalore City, India.Google Scholar
Braterman, P.S. and Cygan, R.T. (2006) Vibrational spectroscopy of brucite: A molecular simulation investigation. American Mineralogist, 91, 1188–1196.CrossRefGoogle Scholar
Djurić, S., Tančić, P., Stojanović, D., Potkonjak, B. and Radukić, G. (1993) Crystallographic data for serbianite, new bores mineral from Ibar Valley, Serbia. P. 46 in: Book of Abstracts of I and II Conference of the Serbia Crystallography Society, Belgrade, Serbia.Google Scholar
Farmer, V.C. (1974) The Infrared Spectra of Minerals. Monograph 4, The Mineralogical Society, London.CrossRefGoogle Scholar
Gallup, R.F. and Coleman, L.B. (1990) Vibrational spectra and the ferroelectric phase transition of colemanite. Physics and Chemistry of Minerals, 17, 271–274.CrossRefGoogle Scholar
Grice, J.D., Gault, R.A. and Van Velthuizen, J. (1996) Penobsquisite: A new borate mineral with a complex framework structure. The Canadian Mineralogist, 34, 657–665.Google Scholar
Guo, F., Wang, J., Liu, F., Yang, Z. and Wu, Y. (2000) Hydrothermal synthesis, characterization and nonlinear optical effect of the orthorhombic phase Ca2B6O11.H2O. Chinese Science Bulletin, 45, 1756–1760.CrossRefGoogle Scholar
Hofmeister, A.M. and Bowey, J.E. (2006) Quantitative infrared spectra of hydrosilicates and related minerals. Monthly Notation of the Royal Astronomical Society, 367, 577–591.Google Scholar
Konnert, J.A., Clark, J.R. and Christ, C.L. (1970) Crystal structure of fabianite, CaB3O5(OH) and comparison with the structure of its synthetic dimorph. Zeitschrift für Kristallographie, 132, 241–254.CrossRefGoogle Scholar
Leech, J.W. and Newman, D.J. (1974) How to Use Groups. Chapman & Hall Ltd, London, and Science Paperbacks, UK.Google Scholar
Libowitzky, E. (2006) Crystal structure dynamics: evidence of diffraction and spectroscopy. Croatia Chemica Acta, 79, 299–309.Google Scholar
Locock, A.J., Pilonen, P.C., Ercit, S.T. and Rowe, R. (2006) New mineral names. American Mineralogist, 91, 216–224.CrossRefGoogle Scholar
Lutz, H.D., Möler, H. and Schmidt, M. (1994) Lattice vibration spectra. Part LXXXII. Brucite-type hydroxides M(OH)2 (M = Ca, Mn, Co, Fe, Cd) – IR and Raman spectra, neutron diffraction of Fe(OH)2 . Journal of Molecular Structure, 328, 121–132.CrossRefGoogle Scholar
Malinko, S.V., Anicic, S., Joksimovic, D., Lisitsyn, A.E., Rudnev, V.V., Dorokhova, G.I., Yamnova, N.A., Vlasov, V.V., Ozol, A.A. and Chukanov, N.V. (2004) Jarandolite Ca[B3O4(OH)3] calcium borate from Serbia: New name and new data. New Data on Minerals, 39, 26–31.Google Scholar
Nikolić, P.M., Djurić, S., Radukić, G., Stojanović, D., Siapkas, D.I. and Zorba, T.T. (1996) Optical and electrical properties of serbianite Ca2B6O8(OH)6 . Bulletin CXIII de Akademie Serbe des Sciences et des Artes, Clase des Sciences techniques, 27, 27–34.Google Scholar
Rosić, A. (2005) Proučavanje kristalografskih svojstava boratnih minerala iz Piskanja (Investigations of crystallographic properties of borate minerals from Piskanja). PhD thesis, Faculty of Mining and Geology, University of Belgrade.Google Scholar
Rousseau, D.L., Bauman, R.P. and Porto, S.P.S. (1981) Normal mode determination in crystals. Journal of Raman Spectroscopy, 10, 253–290.CrossRefGoogle Scholar
Stojanović, D. (1992) New calcium borate hydroxide Ca[B3O4(OH)3]. Pp. 32–33 in: Book of Abstracts of the Conference of Serbian Crystallography Society.Google Scholar
Stojanović, D., Radukić, G. and Radović, R. (1993) Asocijacija bornih minerala u Boljevačkom basenu Srbije (Association of Boron Minerals in the Boljevac Basin in Serbia). Book of Abstracts of the Yugoslav Mineralogy Association JMA (in Serbian).Google Scholar
Weir, C.E. (1966) Infrared spectra of the hydrated borates. Journal of Research of the National Bureau of Standards – A. Physics and Chemistry, 70A, 153–164.Google Scholar
Yamnova, N.A., Egorov-Tismenko, Yu.K., Malinko, S.V., Pusharovski, D.Yu. and Dorohova, G.I. (1994) Kristallicheskaya struktura novogo prirodnogo kalciyevogo gidroborata Ca[B3O4(OH)3] (Crystal structure of a new natural calcium hydroborate). Kristallografiya, 39, 991–993.(in Russian).Google Scholar