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The Staining of Polymers

Published online by Cambridge University Press:  14 March 2018

Ronald W. Smith*
Affiliation:
2450 Clarke Drive, Lake Havasu City, AZ 86403

Extract

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In the beginning there was water-the first stain that delineated structure within a polymeric system. The polymerwas natural rubber (NR) and the system was an air-dried film of natural latex. Grenquist reported in 1929 that a dried film of natural rubber latex soaked in hot water became milky (Figure 1) and, at that stage, the latex particles could be detected by the optical microscope (OM), The contrast mechanism was provided by the absorption of water by the naturally occurring proteinaceous layers present on the congealed NR particle surfaces. There was little demand for polymer staining until the age of electron microscopy.

Type
Research Article
Copyright
Copyright © Microscopy Society of America 2002

References

[1] Grenquist, , Rubber Chemistry & Technol. 2 (1929) 656 Google Scholar
[2] Brown, , J. of Applied Physics, 18 (1947) 273 Google Scholar
[3] Bradford, and Vanderhoff, , J. Colloid Sci. 14 (1959) 543 Google Scholar
[4] Dickenson, , “The Chemistry and Physics of Rubber-Like Substances”, Bateman, L., Ed. John Wiley & Sons, New York, 1963 Chapter 3, Biochemistry of Hevea LatexGoogle Scholar
[5] Kato, , Polymer Engineering Sci. 7 (1967) 38 Google Scholar
[6] Smith, and Andries, , Rubber Chemistry & Technol. 47 (1974) 64 CrossRefGoogle Scholar
[7] Vitali, and Mantani, , Polymer, 21 (1980) 1220 Google Scholar
[8] Trent, et al, J. Polymer Sci. C19 (1981) 315 Google Scholar
[9]Polymer Microscopy”, Sawyer, and Grubb, , 2nd Ed., Chap. & Hall 1995 Google Scholar
[10] Riew, and Smith, , Journal of Polymer Sci. A9 (1971) 2739 CrossRefGoogle Scholar
[11] Kambour, , Polymer (London) 5 (1964) 143 Google Scholar
[12] Kambour, , J. Polymer Sci. A7 (1969) 1393 Google Scholar
[13] Kambour, , Polymer (London) 12 (1973) 237 CrossRefGoogle Scholar
[14] Borggrene, , Polymer 28 (1987) 1499.Google Scholar
[15] Smith, and Folt, , Rubber Chemistry and Technol. 50 (1977) 835 Google Scholar
[16] Kanig, and Neff, , Journal of Colloid and Interface Science 29 (1975) 253 Google Scholar
[17] Cao, , Polymer Communications, 29 (1988) 66 and 67Google Scholar
[18] Nau, , Journal of Material Science, 32 (1997) 5335 Google Scholar
[19] Machedo, , Journal of Polymer Sci. Part A 37 (1999) 1311 3.0.CO;2-Y>CrossRefGoogle Scholar
[20] Dutta, , Rubber Chemistry and Technol. 65 (1992) 932 Google Scholar
[21] Cudby, , Journal of Natural Rubber, 12 (1997) 102 Google Scholar
[22] Holsti-Miettia, Journal of Polymer Engineering and Sci. 34 (1994) 395 Google Scholar