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The Staining of Polymers II

Published online by Cambridge University Press:  14 March 2018

Ronald W. Smith  and
Victoria Bryg
Ronald W. Smith
Affiliation:
Lake Havasu City, AZ
Victoria Bryg
Affiliation:
Richfield, OH

Extract

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E.H. Andrews [1] was the first to produce transmission electron micrographs that differentiated between crystalline and amorphous forms in long chain polymers. Working with thin cast films of cis-polyisoprene {natural rubber (NR)}; he examined them in the unstrained and strained states. Staining the unstrained thin films with osmium tetroxide vapors, he showed that spherulitic crystals were in light contrast whereas the darker contrasted matrix was the amorphous continuum (Figure 1).

Type
Research Article
Information
Microscopy Today , Volume 14 , Issue 1 , January 2006 , pp. 14 - 19
Copyright
Copyright © Microscopy Society of America 2006

References

References:

[1] Andrews, E.H., Journal of Polymer Science, 4, 668 (1966)Google Scholar
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[4] Bryg, Victoria, Unpublished ContributionGoogle Scholar
[5] Claussen, R.C., Rabatic, B.M., Beniash, E., and Stupp, S.I., Polymer Preprints, 44, 152 (2003)Google Scholar
[6] Matsuo, M., Polymer Engineering and Science, 9, 206 (1969)CrossRefGoogle Scholar