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Structural and Chemical Analysis of Hydroxyapatite (HA)-Boron Nitride (BN) Nanocomposites Sintered Under Different Atmospheric Conditions

Published online by Cambridge University Press:  24 August 2017

Feray Bakan ,
Meltem Sezen ,
Merve Gecgin ,
Yapincak Goncu  and
Nuran Ay
Feray Bakan*
Affiliation:
Sabanci University Nanotechnology Research and Application Center (SUNUM), Orhanlı, 34956 Istanbul, Turkey
Meltem Sezen
Affiliation:
Sabanci University Nanotechnology Research and Application Center (SUNUM), Orhanlı, 34956 Istanbul, Turkey
Merve Gecgin
Affiliation:
Department of Materials Science and Engineering, Anadolu University, 26000 Eskisehir, Turkey
Yapincak Goncu
Affiliation:
BORTEK Boron Technologies & Mechatronics Inc., 26110 Eskisehir, Turkey
Nuran Ay
Affiliation:
Department of Materials Science and Engineering, Anadolu University, 26000 Eskisehir, Turkey
*
*Corresponding author. [email protected]
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Abstract

Calcium phosphate derivatives have been widely employed in medical and dental applications for hard tissue repair, as they are the main inorganic constitution of hard tissue; such as bones and teeth. Owing to their excellent osteoconductive and bioactive properties, hydroxyapatite- (HA) based ceramics are the best candidates of this group for medical, bioscience, and dental applications. However, when replacing a bone or tooth, HA is not able to sustain similar mechanical properties. In this study, to improve the mechanical properties, nanoscale hexagonal boron nitride with different compositional percentages was added to the nano HA to form composites. The effect of compositional changes and sintering parameters on microstructural and morphological properties of the ceramic composites was comparatively investigated. Detailed chemical characterization of the composite materials was carried out using X-ray diffraction, Fourier transform infrared spectroscopy, Raman spectroscopy, and energy-dispersive X-ray spectroscopy, whereas scanning electron microscopy and atomic force microscopy investigations were employed to monitor morphological and surface features. Additional transmission electron microscopy investigations were carried out to reveal the nanostructure and crystal structure of the composites.

Keywords

hydroxyapatiteboron nitridenanocompositesinteringcharacterization
Type
Materials Science Applications
Information
Microscopy and Microanalysis , Volume 23 , Issue 5 , October 2017 , pp. 891 - 899
Copyright
© Microscopy Society of America 2017 

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