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Scanning Electron Microscopy (SEM) Energy Dispersive X-ray Spectroscopy (EDS) Mapping and In-situ Observation of Carbonization of Culms of Bambusa Multiplex

Published online by Cambridge University Press:  27 April 2018

Visittapong Yordsri ,
Chanchana Thanachayanont ,
Shunsuke Asahina ,
Yuuki Yamaguchi ,
Masahiro Kawasaki ,
Tetsuo Oikawa ,
Tadashi Nobuchi  and
Makoto Shiojiri
Visittapong Yordsri
Affiliation:
National Metal and Materials Technology Center, 114 Thailand Science Park, Paholyothin Rd., Klong 1, Klong Luang, Pathumthani 12120, Thailand
Chanchana Thanachayanont
Affiliation:
National Metal and Materials Technology Center, 114 Thailand Science Park, Paholyothin Rd., Klong 1, Klong Luang, Pathumthani 12120, Thailand
Shunsuke Asahina
Affiliation:
JEOL Ltd., SM Application Group, Akishima, Tokyo 196-8558, Japan
Yuuki Yamaguchi
Affiliation:
JEOL Ltd., SM Application Group, Akishima, Tokyo 196-8558, Japan
Masahiro Kawasaki*
Affiliation:
JEOL USA Inc., 11 Dearborn Road, Peabody, MA 01960, USA
Tetsuo Oikawa
Affiliation:
4JEOL Asia PTE Ltd., Co Regn No: 199500744W, 2 Corporation Road #01-12, Corporation Place 618494, Singapore
Tadashi Nobuchi
Affiliation:
Kyoto University (emeritus), Yoshidahonmachi, Sakyo Ward, Kyoto 606-8501, Japan
Makoto Shiojiri
Affiliation:
Kyoto Institute of Technology (emeritus), Matsugasaki Hashikamicho, Sakyo Ward, Kyoto 606-8585, Japan
*
*Author for correspondence: Masahiro Kawasaki, E-mail: [email protected]
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Abstract

Green culms of bamboo and charcoal of Bambusa multiplex were investigated by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS) mapping. A dynamic observation of the initial stage of carbonization was also performed in-situ by heating a radial longitudinal section of the bamboo culm at a rate of 20°C/min up to 500°C. EDS mapping of the green bamboo culms detected Si signals in the harder cells such as the epidermis (Ep), cortex (Cor) and vascular bundle sheath (Bs) and between these cells as silicon oxide particles. Appreciable morphological change of the cells occurred in a temperature range of about 300–400°C due to the decomposition of cellulose that is the main component of the bamboo cells. The charcoal of the bamboo culm has a skin layer which originates from the Ep and Cor and the main central cylinder with many openings that originate from the expanded xylem and phloem holes. During carbonization, the Si atoms in the Ep and Cor were segregated as thin silicon oxide layers onto both the sides of the skin layer and the Si included in the Bs fibers and parenchyma cells accumulated near the walls of the openings.

Keywords

bambooBambusa multiplexcarbonizationenergy dispersive X-ray spectroscopy mappingin-situ observation
Type
Biological Science Applications
Information
Microscopy and Microanalysis , Volume 24 , Issue 2 , April 2018 , pp. 156 - 162
Copyright
© Microscopy Society of America 2018 

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Footnotes

*

Present address: Applied Materials, Inc., 3330 Scott Blvd., Bldg 6, Santa Clara, CA 95054, USA.

References

Hasebe, Y, Suzuki, S, Asahina, S and Nokuo, T (2016) Application of non-tiling extra-large field observation and analysis using SEM. Program and Abstract of 11th Asia-Pacific Microscopy Conference, Phuket, p. 272.Google Scholar
Kawamoto, H (2015) Reactions and molecular mechanism of cellulose pyrolysis. Mokuzai Gakkaishi [J Wood Sci] 61, 1–24.Google Scholar
Kawasaki, M, Chen, MJ, Yang, JR, Chiou, WA and Shiojiri, M (2013) Structural analysis of Au/TiO2 thin films deposited on the glass substrate. Appl Phys Lett 102, 091603.Google Scholar
Kawasaki, M, Nobuchi, T, Nakafushi, Y, Nose, M, Shibata, M, Li, P and Shiojiri, M (2017 a) Structural observations and biomechanical measurements of clarinet reeds made from Arundo donax . Microsc. Res. Tech. 80, 959–968.CrossRefGoogle ScholarPubMed
Kawasaki, M, Nobuchi, T, Nose, M and Shiojiri, M (2016) Why are Phragmites australis canes grown in an Udono reed bed the best for reeds of the Japanese wind instrument “hichiriki”? — A structural and biomechanical study. Microscopy Today 24, 46–51.CrossRefGoogle Scholar
Kawasaki, M, Yordsri, V, Thanachayanont, C, Junin, C, Asahina, S, Oikawa, T, Saiki, A and Shiojiri, M (2017 b) Structures of green culms and charcoal of Bambusa multiplex . Microsc Microanal 22(Suppl 1), 1294–1295.Google Scholar
Shimaji, K, Sudo, S and Harada, H (2016) Tissue of Woods. Tokyo: Morikita Publishing (in Japanese).Google Scholar

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