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Nucleation of the α / γ Massive Phase Transformation in Titanium- 48at% Aluminum

Published online by Cambridge University Press:  02 July 2020

J.E. Wittig
Affiliation:
Materials Science and Engineering, Vanderbilt University, Box 1683 Station B, Nashville, TN, 37235
W.H. Hofmeister
Affiliation:
Materials Science and Engineering, Vanderbilt University, Box 1683 Station B, Nashville, TN, 37235
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Extract

Massive phase transformations exhibit a change in crystal structure without a change in composition. Nucleation and growth of this difTUsionless transformation has been studied in numerous systems including Cu-Zn, Ag-Zn and Ag-Al. There is general agreement that heterogeneous grain boundary nucleation occurs with a rational orientation relationship with at least one of the parent grains, although growth of the massive product can often occur with a partially coherent interface.

The typical Ti-48at%Al microstructure is a lamellar structure of hexagonal α2 (DO19 superlattice) and the ordered tetragonal γ phase (Ll0 with c/a = 1.01). Water or ice brine quenching of the high temperature disordered α phase results in a partial massive transformation of a into γ. Electron beam melting has been used to further suppress the equilibrium transformations. However, the current study uses rapid solidification by electromagnetic levitation and twin anvil splat quenching (cooling rates > 106 K/s) to capture earlier stages of the transformation.

Type
Metals and Alloys
Copyright
Copyright © Microscopy Society of America

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References

References:

1)Ayers, J.D. and Joy, D. C., ActaMetall., 20 (1972) 1371Google Scholar
2)Ayers, J.D., Acta Metall., 28 (1980) 1513CrossRefGoogle Scholar
3)Plichta, M.R. and Aaronson, W.I., Acta Metall., 28 (1980) 1041CrossRefGoogle Scholar
4)Plichta, M.R., Clark, W.A.T., Aaronson, W.I., Metallurgical Transactions A 15 (1984) 427CrossRefGoogle Scholar
5)Wang, P., Viswanathan, G.B., and Vasudevan, V.K., Metallurgical Transactions, 23A (1992) 690CrossRefGoogle Scholar
6)Zhang, X. D., et al., Acta mater., 44, (1996) 3723CrossRefGoogle Scholar
7) This research was supported by the National Science Foundation, DMR-9616748Google Scholar