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Near-Field Optical Spectroscopy: Enhancing the Light Budget

Published online by Cambridge University Press:  02 July 2020

M.A. Paesler
Affiliation:
Physics Department, North Carolina State University, Raleigh, NC27695-8202, USA Institute of Applied Photophysics, Technical University Dresden, D-01069, Dresden, Germany
H.D. Hallen
Affiliation:
Physics Department, North Carolina State University, Raleigh, NC27695-8202, USA
B.I. Yakobson
Affiliation:
Physics Department, North Carolina State University, Raleigh, NC27695-8202, USA
C.J. Jahncke
Affiliation:
Physics Department, North Carolina State University, Raleigh, NC27695-8202, USA
P.O. Boykin
Affiliation:
Physics Department, North Carolina State University, Raleigh, NC27695-8202, USA
A. Meixner
Affiliation:
Institute of Applied Photophysics, Technical University Dresden, D-01069, Dresden, Germany
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Extract

The near-field scanning optical microscope, or NSOM, provides spectroscopists with resolution beneath the diffraction limit. In the NSOM, an optical aperture smaller than the wavelength λ of the probe radiation is scanned in the near-field of a sample. Pixels are serially gathered and then constituted as a computer-generated image. Spectroscopic NSOM investigations demonstrating sub-λ, resolution include studies of photoluminescence, Raman spectroscopy, and single molecule fluorescence. Results of nano-Raman spectroscopy on semiconducting Rb-doped KTP are shown in figure 1. Figure la is a topographic image of the sample showing a square Rb-doped region in an otherwise undoped sample. Figure lc is a NSOM region of the corner of the doped region, and figure lb is an image of the same region taken within a Raman line. While these data do provide sub-λ spectroscopic resolution and other interesting features, the weak signal provided by current NSOM technologies and the low quantum efficiency of the Raman effect necessitated development of a very low-drift microscope and inconveniently long collection times.

Type
Optical Microanalysis
Copyright
Copyright © Microscopy Society of America 1997

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References

1. Paesler, M.A. and Moyer, P.J., Near-field Optics:Theory, Instrumentation, and Applications, John Wiley & Sons, NY 1996.Google Scholar

2. Jahncke, C L. and Hallen, H.D., LEOS 96 conference proceedings vol. 1, pp. 176177.Google Scholar

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5. Research supported by US Army (DAAH04-93-G-164 and DAAH04-G-064) and NSF (DMR-9300041).Google Scholar