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Microstructural Characterization of α2 + γ Titanium Aluminides

Published online by Cambridge University Press:  02 July 2020

D. J. Larson
Affiliation:
Metals and Ceramics Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831-6376
M. K. Miller
Affiliation:
Metals and Ceramics Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831-6376
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Extract

Two-phase α2+γ TiAl alloys with microalloying additions, Fig. 1, are of interest due to the high strength-to-weight ratio they can provide in automotive and aircraft applications. In boron-doped α2+γTiAl containing Cr, Nb, and W, the B levels were found to be significantly depleted below the nominal alloy content in both the α2 andγ phases. The boron solubilities in the γ and α2 phases were 0.011 ± 0.005 at. % B and 0.003 ± 0.005 at. % B, respectively in Ti-47% Al-2% Cr-1.8% Nb-0.2% W-0.15 % B that was aged for 2 h at 900°C (base alloy). The majority of the B was in a variety of borides including TiB, TiB2 and a Cr-enriched (Ti,Cr)2B precipitate. With the exception of the smaller (< 50 nm thick) Cr-enriched (Ti,Cr)2B precipitates, Fig. 2, most of the borides were larger than ∼100 nm. A significant proportion of the microalloying additions is in these borides, Table 1.

Type
Phase Transformations in Metals and Alloys
Copyright
Copyright © Microscopy Society of America 1997

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References

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4. This research was sponsored by the Division of Materials Sciences, U. S. Department of Energy, under contract DE-AC05-96OR22464 with Lockheed Martin Energy Research Corp and was conducted utilizing the Shared Research Equipment (SHaRE) User Program facilities at Oak Ridge National Laboratory.Google Scholar