Hostname: page-component-78c5997874-mlc7c Total loading time: 0 Render date: 2024-11-05T02:35:38.722Z Has data issue: false hasContentIssue false
  • English
  • Français

Investigation of ORR Performances on Graphene/Phthalocyanine Nanocomposite in Neutral Medium

Published online by Cambridge University Press:  27 May 2019

Moumita Mukherjee ,
Madhupriya Samanta ,
Gour P. Das  and
Kalyan K. Chattopadhyay
Moumita Mukherjee
Affiliation:
Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700032, India
Madhupriya Samanta
Affiliation:
Department of Electronics & Telecommunication Engineering, Jadavpur University, Kolkata 700032, India School of Materials Science & Nanotechnology, Jadavpur University, Kolkata 700032, India
Gour P. Das*
Affiliation:
Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700032, India
Kalyan K. Chattopadhyay*
Affiliation:
School of Materials Science & Nanotechnology, Jadavpur University, Kolkata 700032, India
*
*Authors for correspondence: Gour P. Das, E-mail: [email protected]; Kalyan K. Chattopadhyay, E-mail: [email protected]
*Authors for correspondence: Gour P. Das, E-mail: [email protected]; Kalyan K. Chattopadhyay, E-mail: [email protected]
Get access

Abstract

The drive to replace scarce and expensive Pt-based electrocatalysts for oxygen reduction reaction (ORR) has led to the development of a group of electrocatalysts composed of transition-metal ion centers coordinated with four nitrogen groups (M-N4). Among these, metal phthalocyanines (MPcs), due to low cost of preparation, highly conjugated structure as well as high thermal and chemical stability, have received a great interest. The catalytic activity of MPcs can be improved by employing conducting supports. Here, in this report, we have solvothermally synthesized graphene-supported zinc phthalocyanine nanostructures, and their ORR kinetics and mechanism have been investigated in neutral solution (pH = 7) by using the rotating disk electrode technique. The as-synthesized nanocomposite followed a 4e− reduction pathway. The onset potential (−0.04 V versus Ag/AgCl) found in this work can be comparable with other state-of-the-art material, demonstrating good performance in neutral solution. The fascinating performance leads the nanocomposite material toward future energy applications.

Keywords

neutral mediumORRRGOzinc phthalocyanine
Type
Materials Applications
Information
Microscopy and Microanalysis , Volume 25 , Issue 6 , December 2019 , pp. 1416 - 1421
Copyright
Copyright© Microscopy Society of America 2019 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

†

Present address: Department of Metallurgical and Materials Engineering, Indian Institute of Technology, Kharagpur 721 302, West Bengal, India.

References

Ahmed, J, Yuan, Y, Zhoud, L & Kima, S (2012). Carbon supported cobalt oxide nanoparticles–iron phthalocyanine as alternative cathode catalyst for oxygen reduction in microbial fuel cells. J Power Sources 208, 170–175.Google Scholar
Cao, C, Wei, L, Su, M, Gang Wang, G & Shen, J (2016). Spontaneous bubble-template assisted metal–polymeric framework derived N/Co dual-doped hierarchically porous carbon/Fe3O4 nanohybrids: Superior electrocatalyst for ORR in biofuel cells. J Mater Chem A 4, 9303–9310.Google Scholar
Choi, HJ, Ashok Kumar, N & Baek, JB (2015). Graphene supported non-precious metalmacrocycle catalysts for oxygen reduction reaction in fuel cells. Nanoscale 7, 6991–6998.Google Scholar
Chu, Y, Gu, L, Ju, X, Du, H, Zhao, J & Qu, K (2018). Carbon supported multi-branch nitrogen-containing polymers as oxygen reduction catalysts. Catalysts 8, 245–266.Google Scholar
Cui, L, Lv, G, Dou, Z & He, X (2013). Fabrication of iron phthalocyanine/graphene micro/nanocomposite by solvothermally assisted π–π assembling method and its application for oxygen reduction reaction. Electrochim Acta 106, 272–278.Google Scholar
Ejaz, A & Jeon, S (2018). The individual role of pyrrolic, pyridinic and graphitic nitrogen in the growth kinetics of Pd NPs on N-rGO followed by a comprehensive study on ORR. Int J Hydrogen Energy 43, 5690–5702.Google Scholar
Geim, AK & Novoselov, KS (2007). The rise of graphene. Nat Mater 6, 183–191.Google Scholar
Hummers, WS Jr. & Offeman, RE (1958) Preparation of graphitic oxide. J Am ChemSoc 80, 1339.Google Scholar
Jasinski, R (1964). A new fuel cell cathode catalyst. Nature 201, 1212–1213.Google Scholar
Jiang, Y, Lu, Y, Lv, X, Han, D, Zhang, Q, Niu, L & Chen, W (2013). Enhanced catalytic performance of Pt-free iron phthalocyanine by graphene support for efficient oxygen reduction reaction. ACS Catal 3, 1263–1271.Google Scholar
Koca, A, Kalkan, A & Bayır, ZA (2011). Electrocatalytic oxygen reduction and hydrogen evolution reactions on phthalocyanine modified electrodes: Electrochemical, in situ spectroelectrochemical, and in situ electrocolorimetric monitoring. Electrochim Acta 56, 5513–5525.Google Scholar
Li, X, Cai, W, An, J, Kim, S, Nah, J, Yang, D, Piner, R, Velamakanni, A, Jung, I, Tutuc, E, Banerjee, SK, Colombo, L & Ruoff, RS (2009). Large-area synthesis of high-quality and uniform graphene films on copper foils. Science 324, 1312–1314.Google Scholar
Mukherjee, M, Samanta, M, Ghorai, UK, Murmu, S, Das, GP & Chattopadhyay, KK (2018). One pot solvothermal synthesis of ZnPc nanotube and its composite with RGO: A high performance ORR catalyst in alkaline medium. Appl Suf Sci 449, 144–151.Google Scholar
Nagaiah, TC, Maljusch, A, Chen, X, Bron, M & Schuhmann, W (2009). Visualization of the local catalytic activity of electrodeposited Pt–Ag catalysts for oxygen reduction by means of SECM. Chem Phys Chem 10, 2711–2718.Google Scholar
Reina, A, Jia, X, Ho, J, Nezich, D, Son, H, Bulovic, V, Dresselhaus, MS & Kong, J (2009). Large area, Few-layer graphene films on arbitrary substrates by chemical vapor deposition. Nano let 9, 30–35.Google Scholar
Roy, D, Das, NM, Shakti, N & Gupta, PS (2014). Comparative study of optical, structural and electrical properties of zinc phthalocyanine Langmuir–Blodgett thin film on annealing. RSC Adv 4, 42514–42522.Google Scholar
Sakamoto, K & Ohno-Okumura, E (2009). Synthesis and functional properties of phthalocyanines. Materials (Basel) 2, 1127–1180.Google Scholar
Sedona, F, Marino, MD, Forrer, D, Vittadini, A, Casarin, M, Cossaro, A, Floreano, L, Verdini, A & Sambi, M (2012). Tuning the catalytic activity of Ag(110)-supported Fe phthalocyanine in the oxygen reduction reaction. Nat Mater 11, 970–977.Google Scholar
Shinagawa, T & Takanabe, K (2016). Electrolyte engineering toward efficient hydrogen production electrocatalysis with oxygen-crossover regulation under densely buffered near-neutral pH conditions. J Phys Chem C 120, 1785–1794.Google Scholar
Tong, X, Xia, X, Guo, C, Zhang, Y, Tu, J, Fan, HJ & Guo, X-Y (2015). Efficient oxygen reduction reaction using mesoporous Ni-doped Co3O4nanowire array electrocatalysts. J Mater Chem A 3, 18372–18379.Google Scholar
Vincent, I & Bessarabov, D (2016). Electrochemical characterization and oxygen reduction kinetics of Cu-incorporated cobalt oxide catalyst. Int J Electrochem Sci 11, 8002–8015.Google Scholar
Wen, Z, Ci, S, Zhang, F, Feng, X, Cui, S, Mao, S, Luo, S, He, Z & Chen, J (2012). Nitrogen-enriched core-shell structured Fe/Fe3C-C nanorods as advanced electrocatalysts for oxygen reduction reaction. Adv Mater 24, 1399–1404.Google Scholar
Xu, X, Wang, M, Liu, Y, Lu, T & Pan, L (2016). Metal–organic framework-engaged formation of a hierarchical hybrid with carbon nanotube inserted porous carbon polyhedra for highly efficient capacitive deionization. J Mater Chem A 4, 5467–5473.Google Scholar
Yang, L, Jiang, S, Zhao, Y, Zhu, L, Chen, S, Wang, X, Wu, Q, Ma, J, Ma, Y & Hu, Z (2011). Boron-doped carbon nanotubes as metal-free electrocatalysts for the oxygen reduction reaction. Angew Chem Int Ed Engl 50, 7132–7135.Google Scholar
Zhang, W, Shaikh, AU, Tsui, EY & Swager, TM (2009). Cobalt porphyrin functionalized carbon nanotubes for oxygen reduction. Chem Mater 21, 3234–3241.Google Scholar
Zhang, C, Hao, R, Yin, H, Liu, F & Hou, Y (2012). Iron phthalocyanine and nitrogen-doped graphene composite as a novel non-precious catalyst for the oxygen reduction reaction. Nanoscale 4, 7326–7329.Google Scholar
Zhang, S, Zhang, H, Hua, X & Chen, S (2015). Tailoring molecular architectures of Fe phthalocyanine on nanocarbon supports for high oxygen reduction performance. J Mater Chem A 3, 10013–10019.Google Scholar
Zhu, S, Hu, X, Zhang, L & Shao, M (2016). Impacts of perchloric acid, nafion, and alkali metal ions on oxygen reduction reaction kinetics in acidic and alkaline solutions. J Phys Chem C 120, 27452–27461.Google Scholar