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Interfacial Segregation in Oxide Scales on Nicrai-Based Alloys

Published online by Cambridge University Press:  02 July 2020

K. Prüβner
Affiliation:
Metals & Ceramics Division, Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, TN37831
K. B. Alexander
Affiliation:
Metals & Ceramics Division, Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, TN37831
B. A. Pint
Affiliation:
Metals & Ceramics Division, Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, TN37831
P. F. Tortorelli
Affiliation:
Metals & Ceramics Division, Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, TN37831
I. G. Wright
Affiliation:
Metals & Ceramics Division, Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, TN37831
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Extract

Previous studies addressing the segregation of reactive elements in protective oxide scales and their beneficial effect on scale adhesion have primarily concentrated on primary alumina-formers (e.g. β-NiAl + FeCrAl).In our study the oxidation behaviour of three NiCrAl alloys, which form complex scales was studied in air at 1423 K and at 1473 K, both in isothermal (100 h) and in cyclic oxidation (100 x lh). The composition (in at.-%) of these alloys is the following: General Electric alloy René N5 (64.9 Ni, 7.8 Cr, 13.9 Al, 0.1 Fe, 2.1 Ta, 0.05 Hf, 1.6 W, 1.0 Re, 0.15 Si, 7.3 Co, 0.9 Mo, 0.003 Y, 0.003 Zr, 4 ppm S, 0.25 C), Ni-7Cr-6.5Al+Y (80.1 Ni, 7.2 Cr, 12.5 Al, 0.01 Fe, 0.14 Si, 0.012 Y, 18 ppm S, 0.05 C) and Ni-10Cr-10Al+Y (71.2 Ni, 9.9 Cr, 18.8 Al, 0.01 Fe, 0.02 Si, 0.041 Y, 16 ppm S, 0.04 C).

Type
Oxidation, Corrosion, and Protective Coatings
Copyright
Copyright © Microscopy Society of America 1997

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References

Pint, B. A., Oxid. Met. 45 (1996) 110.1007/BF01046818CrossRefGoogle Scholar
Giggins, C. S., Pettit, F. S., J. Electrochem. Soc. 118 (1971) 178210.1149/1.2407837CrossRefGoogle Scholar
Research at the Oak Ridge National Laboratory (ORNL) SHaRE User Facility was sponsored by the Division of Materials Sciences, U.S. Department of Energy, under contract DE-AC05-96OR22 464 with Lockheed Martin Energy Research Corp., and by an appointment (KP) to the ORNL Postdoctoral Research Associates Program, which is administered jointly by the Oak Ridge Institute for Science and Education and ORNL.Google Scholar