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Cu Nanoparticle Formation: Copper Redistribution During NaCl Solution Corrosion of Al-Cu-Mg Alloys

Published online by Cambridge University Press:  02 July 2020

R. G. Ford
Affiliation:
Science & Engineering of Materials Program, Center for Solid State Science, Tempe, AZ85287-1704
R. W. Carpenter
Affiliation:
Science & Engineering of Materials Program, Center for Solid State Science, Tempe, AZ85287-1704
K. Sieradzki
Affiliation:
Mechanical & Aerospace Engineering Department, Arizona State University, Tempe, AZ85287-1704
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Extract

Aluminum-copper-magnesium alloys also containing manganese and iron (commercial designation 2024) are susceptible to marine corrosion and stress corrosion cracking. Susceptibility depends on heat treatment, and is thought to involve redistribution of copper from within the microstructure onto the surface of the corroding alloy, but few direct observations of the mechanism have been made. Copper can be distributed in several ways throughout the microstructure, which complicates mechanism studies. The primary age-hardening phase is Al2CuMg (orthorhombic; a=4.01, b=9.25, c=7.15 Å) which appears as more or less large equiaxed S particles at equilibrium, and as metastable S’ plates after aging for shorter times at lower temperature (∼190°C). In addition, ubiquitous so-called “dispersoids” containing copper and manganese (prolate spheroid morphology) or iron (irregular “blocky” morphology) do not go into solution when the alloy is solid state homogenized (-495 °C) and are always present in the microstructure. All of these phases are copper-rich sources for surface redistribution relative to the matrix during corrosion.

Type
Nanophase and Amorphous Materials
Copyright
Copyright © Microscopy Society of America

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References

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4. This research is supported by the U.S. Air Force Office of Scientific Research, under contract F49620-96-1-0475.Google Scholar