Hostname: page-component-cd9895bd7-dk4vv Total loading time: 0 Render date: 2024-12-24T13:46:55.711Z Has data issue: false hasContentIssue false

Selected-Area Growth of Carbon Nanotubes by the Combination of Focused Ion Beam and Chemical Vapor Deposition Techniques

Published online by Cambridge University Press:  21 November 2003

Jun Jiao
Affiliation:
Department of Physics, Portland State University, Portland, Oregon 97201, USA
Lifeng Dong
Affiliation:
Department of Physics, Portland State University, Portland, Oregon 97201, USA
Sean Foxley
Affiliation:
Department of Physics, Portland State University, Portland, Oregon 97201, USA
Catherine L. Mosher
Affiliation:
Department of Physics, Portland State University, Portland, Oregon 97201, USA
David W. Tuggle
Affiliation:
Department of Physics, Portland State University, Portland, Oregon 97201, USA
Get access

Abstract

In this article, we report a technique for growing carbon nanotubes in a more controllable fashion, which enables us to synthesize nanotubes directly in various forms of designed patterns. This nanofabrication process is based on a combination of focused ion beam (FIB) and chemical vapor deposition (CVD) techniques. In this process, arrays of conductive patterns were first deposited on silicon substrates by directing a gaseous compound (C9H16Pt) via the capillary needle-sized nozzles within a FIB system. The substrates were then coated with catalyst and further modified by the FIB to localize the position of the catalyst. Finally, the growth of carbon nanotubes on the designed substrates was carried out by CVD of hydrocarbon gases. This fabrication technique has the advantage of positioning carbon nanotubes in selected locations. This may open up opportunities for the direct synthesis of carbon nanotubes onto almost any substrate material, thus allowing fabrication of carbon nanotube-based devices.

Type
Materials Applications
Copyright
© 2003 Microscopy Society of America

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Cassell, A., Franklin, N., Chan, E., Han, J., & Dai, H.J. (1999). Directed growth of free-standing single-walled carbon nanotubes. J Am Chem Soc 121, 79757976.CrossRefGoogle Scholar
Collins, P.G., Arnold, M.S., & Avouris, P. (2001). Engineering carbon nanotubes and nanotube circuits using electrical breakdown. Science 292, 706709.CrossRefGoogle Scholar
Dong, L.F., Jiao, J., Foxley, S., Mosher, C.L., & Tuggle, D.W. (2002). Effects of hydrogen on the formations of carbon nanotubes by chemical vapor deposition. J Nanosci Nanotech 2, 155160.CrossRefGoogle Scholar
Jiao, J. & Seraphin, S. (2000). Single-walled tubes and encapsulated nanoparticles: Comparison of structural properties of carbon nanoclusters prepared by three different methods. J Phys Chem Sol 61, 10551067.CrossRefGoogle Scholar
Kataura, H., Kimura, A., Ohtsuka, Y., Suzuki, S., Maniwa, Y., Hanyu, T., & Achiba, Y. (1998). Formation of thin single-wall carbon nanotubes by laser vaporization of Rh/Pd-graphite composite rod. Jpn J Appl Phys 37, L616L618.CrossRefGoogle Scholar
Liu, C., Fan, Y.Y., Liu, M., Cong, H.T., Cheng, H.M., & Dresselhaus, M.S. (1999). Hydrogen storage in single-walled carbon nanotubes at room temperature. Science 286, 11271129.CrossRefGoogle Scholar
Nishijima, H., Akita, S., & Nakayama, Y. (1999). Novel process for fabricating nanodevices consisting of carbon nanotubes. Jpn J Appl Phys 38, 72477252.CrossRefGoogle Scholar
Rinzler, A.G., Hafner, J.H., Nikolaev, P., Lou, L., Kim, S.G., Tomanek, D., Norlander, P., Colbert, D.T., & Smalley, R.E. (1995). Unraveling nanotubes: Field emission from an atomic wire. Science 269, 15501553.CrossRefGoogle Scholar
Ruoff, R.S. & Lorents, D.C. (1995). Mechanical and thermal properties of carbon nanotubes. Carbon 33, 925930.CrossRefGoogle Scholar
Saito, R., Dresselhaus, G., & Dresselhaus, M.S. (1993). Electronic structure of double-layer graphene tubules. J Appl Phys 73, 494500.CrossRefGoogle Scholar
Treacy, M.M.J., Ebbesen, T.W., & Gibson, J.M. (1996). Exceptionally high Young's modulus observed for individual carbon nanotubes. Nature 381, 678680.CrossRefGoogle Scholar