Hostname: page-component-78c5997874-m6dg7 Total loading time: 0 Render date: 2024-11-09T05:41:18.565Z Has data issue: false hasContentIssue false

Microstructural Characterization of Carbon Nanotubes (CNTs)-Reinforced Nickel Matrix Nanocomposites

Published online by Cambridge University Press:  24 September 2018

Sónia Simões*
Affiliation:
CEMMPRE, Department of Metallurgical and Materials Engineering, University of Porto, R. Dr. Roberto Frias, 4200-465 Porto, Portugal INEGI—Institute of Science and Innovation in Mechanical and Industrial Engineering, R. Dr. Roberto Frias, 4200-465 Porto, Portugal
Íris Carneiro
Affiliation:
CEMMPRE, Department of Metallurgical and Materials Engineering, University of Porto, R. Dr. Roberto Frias, 4200-465 Porto, Portugal
Filomena Viana
Affiliation:
CEMMPRE, Department of Metallurgical and Materials Engineering, University of Porto, R. Dr. Roberto Frias, 4200-465 Porto, Portugal INEGI—Institute of Science and Innovation in Mechanical and Industrial Engineering, R. Dr. Roberto Frias, 4200-465 Porto, Portugal
Marcos A. L. Reis
Affiliation:
Faculdade de Ciências Exatas e Tecnologia, Universidade Federal do Pará, Abaetetuba, Pará 68440-000,Brazil
Manuel F. Vieira
Affiliation:
CEMMPRE, Department of Metallurgical and Materials Engineering, University of Porto, R. Dr. Roberto Frias, 4200-465 Porto, Portugal INEGI—Institute of Science and Innovation in Mechanical and Industrial Engineering, R. Dr. Roberto Frias, 4200-465 Porto, Portugal
*
Author for correspondence: Sónia Simões, E-mail: [email protected]
Get access

Abstract

This research focuses on the microstructural characterization of nickel matrix composites reinforced by carbon nanotubes (CNTs). The nanocomposites were produced by a conventional powder metallurgy process and the dispersion of CNTs and mixture with nickel powders was performed in a single step by ultrasonication. Microstructural characterization of Ni–CNT nanocomposites was performed by scanning and transmission electron microscopy, electron backscattered diffraction, high-resolution transmission electron microscopy, selected area electron diffraction, and fast Fourier transform analyses. This characterization revealed CNTs embedded in the nickel grains and mainly presented as clusters at the grain boundaries. CNTs hinder recrystallization during sintering, and dislocation cells and subgrains form as a result of the recovery process.

Type
Material Sciences
Copyright
Copyright © Microscopy Society of America 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Bakshi, SR Agarwal, AN (2011) An analysis of the factors affecting strengthening in carbon nanotube reinforced aluminum composites. Carbon 49, 533544.Google Scholar
Bakshi, SR, Lahiri, D Agarwal, A (2010) Carbon nanotube reinforced metal matrix composites—a review. Int Mater Rev 55, 4164.Google Scholar
Baughman, RH, Zakhidov, AA de Heer, WA (2002) Carbon nanotubes—the route toward applications. Science 297, 787792.Google Scholar
Chen, B, Li, S, Imai, H, Jia, L, Umeda, J, Takahashi, M Kondoh, K (2015) Load transfer strengthening in carbon nanotubes reinforced metal matrix composites via in-situ tensile tests. Compos Sci Technol 113, 18.Google Scholar
Choi, HJ, Min, BH, Shin, JH Bae, DH (2011 a) Strengthening in nanostructured 2024 aluminum alloy and its composites containing carbon nanotubes. Compos Part A Appl Sci Manuf 42, 14381444.10.1016/j.compositesa.2011.06.008Google Scholar
Choi, HJ, Shin, JH Bae, DH (2011 b) Grain size effect on the strengthening behavior of aluminum-based composites containing multi-walled carbon nanotubes. Compos Sci Technol 71, 16991705.Google Scholar
Dong, S, Zhou, J, Hui, D, Wuang, Y Zang, S (2015 a) Size dependent strengthening mechanisms in carbon nanotube reinforced metal matrix composites. Compos Part A Appl Sci Manuf 68, 356364.Google Scholar
Dong, S, Zhou, J, Liu, H, Wua, Y Qi, D (2015 b) The strengthening effect of carbon nanotube in metal matrix composites considering interphase. Mech Mater 91, 111.Google Scholar
George, R, Kashyap, KT, Rahul, R Yamdagni, S (2005) Strengthening in carbon nanotube/aluminium (CNT/Al) composites. Scr Mater 53, 11591163.Google Scholar
Hwang, JY, Lim, BK, Tiley, J, Banerjee, R Hong, SH (2013) Interface analysis of ultra-high strength carbon nanotube/nickel composites processed by molecular level mixing. Carbon 57, 282287.Google Scholar
Kondoh, K, Threrujirapapong, T, Imai, H, Umeda, J Fugetsu, B (2009) Characteristics of powder metallurgy pure titanium matrix composite reinforced with multiwall carbon nanotubes. Compos Sci Technol 69, 10771081.Google Scholar
Li, S, Sun, B, Imai, H Kondoh, K (2013) Powder metallurgy Ti-TiC metal matrix composites prepared by in situ reactive processing of Ti-VGCFs system. Carbon 61, 216228.Google Scholar
Li, C-D, Wang, X-J, Liu, W-Q, Wu, K, Shi, H-L, Ding, C Zheng, M-Y (2015) Microstructure and mechanical properties of magnesium matrix composite reinforced with carbon nanotubes by ultrasonic vibration. Rare Met. doi: 10.1007/s12598-015-0561-y.Google Scholar
Nam, DH, Cha, SI Cha, Lim, HM, Han, DS Hong, SH (2012) Synergistic strengthening by load transfer mechanism and grain refinement of CNT/Al-Cu composites. Carbon 50, 24172423.Google Scholar
Popov, VN (2004) Carbon nanotubes: Properties and application. Mater Sci Eng R 43, 61102.Google Scholar
Simões, S, Viana, F, Reis, MAL Vieira, MF (2014) Improved dispersion of carbon nanotubes in aluminum nanocomposites. Compos Struct 108, 9921000.Google Scholar
Simões, S, Viana, F, Reis, MAL Vieira, MF (2015) Influence of dispersion/mixture time on mechanical properties of Al-CNTs nanocomposites. Compos Struct 126, 114122.Google Scholar
Simões, S, Viana, F, Reis, MAL Vieira, MF (2016) Microstructural characterization of aluminum-carbon nanotube nanocomposites produced using different dispersion methods. Microsc Microanal 22, 725732.Google Scholar
Simões, S, Viana, F, Reis, MAL Vieira, MF (2017) Aluminum and nickel matrix composites reinforced by CNTs: Dispersion/mixture by ultrasonication. Metals 7, 279.Google Scholar
Sinnott, SB Andrews, R (2001) Carbon nanotubes: Synthesis, properties, and applications. Crit Rev Solid State Mater Sci 26, 145249.Google Scholar
Suaréz, S, Lasserre, F Mucklich, F (2013) Mechanical properties of MWNT/Ni bulk composites: Influence of the microstructural refinement on the hardness. Mater Sci Eng 587, 381386.Google Scholar
Suaréz, S, Soldera, F, Oliver, CG, Acevedo, D Mucklich, F (2012) Thermomechanical behavior of bulk Ni/MWNT composites produced via powder metallurgy. Adv Eng Mater 14, 499502.Google Scholar
Tjong, SC (2009) Carbon Nanotube Reinforced Nanocomposites. Weinheim: Wiley-VCH Verlag GmbH & Co KGaA.Google Scholar
Zhang, Z Chen, DL (2008) Contribution of Orowan strengthening effect in particulate-reinforced metal matrix nanocomposites. Mater Sci Eng A 483-484, 148152.Google Scholar