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Electron-Beam-Induced Carbon Contamination on Silicon: Characterization Using Raman Spectroscopy and Atomic Force Microscopy

Published online by Cambridge University Press:  24 December 2009

Deborah Lau ,
Anthony E. Hughes ,
Tim H. Muster ,
Timothy J. Davis  and
A. Matthew Glenn
Deborah Lau*
Affiliation:
CSIRO Materials Science & Engineering, Private Bag 33, Clayton South, Victoria 3169, Australia CSIRO Future Manufacturing Flagship, Gate 5 Normanby Road, Clayton, Victoria 3168, Australia
Anthony E. Hughes
Affiliation:
CSIRO Materials Science & Engineering, Private Bag 33, Clayton South, Victoria 3169, Australia CSIRO Future Manufacturing Flagship, Gate 5 Normanby Road, Clayton, Victoria 3168, Australia
Tim H. Muster
Affiliation:
CSIRO Materials Science & Engineering, Private Bag 33, Clayton South, Victoria 3169, Australia CSIRO Future Manufacturing Flagship, Gate 5 Normanby Road, Clayton, Victoria 3168, Australia
Timothy J. Davis
Affiliation:
CSIRO Materials Science & Engineering, Private Bag 33, Clayton South, Victoria 3169, Australia CSIRO Future Manufacturing Flagship, Gate 5 Normanby Road, Clayton, Victoria 3168, Australia
A. Matthew Glenn
Affiliation:
CSIRO Minerals, Box 312, Clayton South, Victoria 3169, Australia
*
Corresponding author. E-mail: [email protected]
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Abstract

Electron-beam-induced carbon film deposition has long been recognized as a side effect of scanning electron microscopy. To characterize the nature of this type of contamination, silicon wafers were subjected to prolonged exposure to 15 kV electron beam energy with a probe current of ∼300 pA. Using Raman spectroscopy, the deposited coating was identified as an amorphous carbon film with an estimated crystallite size of 125 Å. Using atomic force microscopy, the cross-sectional profile of the coating was found to be raised and textured, indicative of the beam raster pattern. A map of the Raman intensity across the coating showed increased intensity along the edges and at the corner of the film. The intensity profile was in excess of that which could be explained by thickness alone. The enhancement was found to correspond with a modeled local field enhancement induced by the coating boundary and showed that the deposited carbon coating generated a localized disturbance in the opto-electrical properties of the substrate, which is compared and contrasted with Raman edge enhancement that is produced by surface structure in silicon.

Keywords

electron microscopycarbon depositionamorphous thin filmsRaman spectroscopy
Type
Thick and Thin Films: Standards and Analysis
Information
Microscopy and Microanalysis , Volume 16 , Issue 1 , February 2010 , pp. 13 - 20
Copyright
Copyright © Microscopy Society of America 2010

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