Hostname: page-component-586b7cd67f-vdxz6 Total loading time: 0 Render date: 2024-11-27T01:50:08.006Z Has data issue: false hasContentIssue false
  • English
  • Français

Novel calcium phosphate ceramics prepared by powder sintering and crystallization of glasses in the pyrophosphate region

Published online by Cambridge University Press:  31 January 2011

Toshihiro Kasuga  and
Yoshihiro Abe
Toshihiro Kasuga*
Affiliation:
Department of Materials Science and Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466–8555, Japan
Yoshihiro Abe
Affiliation:
Department of Materials Science and Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466–8555, Japan
*
a)[email protected].
Get access

Abstract

Silica-free phosphate glasses containing small amounts of Na2O and TiO2 with the composition of Ca/P = 1 in atomic ratio were obtained. When powder compacts of the glasses were heated at 850 °C, they crystallized and subsequently sintered, resulting in glass-ceramics containing β–Ca3(PO4)2 and β–Ca2P2O7 crystalline phases. The glass-ceramics show a relatively high fracture toughness of KIC ≈ 2 MPa m0.5. By soaking in simulated body fluid at 37 °C, a calcium phosphate phase was formed newly on the surface of the glass-ceramics.

Type
Articles
Information
Journal of Materials Research , Volume 13 , Issue 12 , December 1998 , pp. 3357 - 3360
Copyright
Copyright © Materials Research Society 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1.Kitsugi, T., Yamamuro, T., Nakamura, T., Kotani, S., Kokubo, T., and Takeuchi, H., Biomaterials 14, 216 (1993).CrossRefGoogle Scholar
2.Kitsugi, T., Yamamuro, T., Nakamura, T., and Oka, M., Biomaterials 16, 1101 (1995).CrossRefGoogle Scholar
3.Doremus, R. H., J. Mater. Sci. 27, 285 (1992).CrossRefGoogle Scholar
4.Hench, L. L., J. Am. Ceram. Soc. 74, 1487 (1991).CrossRefGoogle Scholar
5.Jarcho, M., Kay, J. F., Gumaer, K. I., Doremus, R. H., and Drobeck, H. P., J. Bioeng. 1, 79 (1977).Google Scholar
6.Tracy, B. and Doremus, R. H., J. Biomed. Mater. Res. 18, 719 (1984).CrossRefGoogle Scholar
7.Hench, L. L. and Anderson, Ö., An Introduction to Bioceramics (World Scientific, Singapore, 1993), pp. 41–62.CrossRefGoogle Scholar
8.Nakamura, T., Yamamuro, T., Higashi, S., Kokubo, T., and Ito, S., J. Biomed. Mater. Res. 19, 685 (1985).CrossRefGoogle Scholar
9.Blencke, B. A., Pfeil, E., Brömer, H., and Käs, H. H., Chir. Forum Exp. Klin. Forsch, 107 (1973).Google Scholar
10.Höland, W., Vogel, W., Nauman, K., and Gummel, J., J. Biomed. Mater. Res. 19, 303 (1985).CrossRefGoogle Scholar
11.Li, R., Clark, A. E., and Hench, L. L., J. Appl. Biomater. 2, 231 (1991).CrossRefGoogle Scholar
12.Kasuga, T., Yoshida, M., Ikushima, A. J., Tsuchiya, M., and Kusakari, H., J. Am. Ceram. Soc. 75, 1884 (1992).CrossRefGoogle Scholar
13.Kasuga, T., Ota, Y., Tsuji, K., and Abe, Y., J. Am. Ceram. Soc. 79, 1821 (1996).CrossRefGoogle Scholar
14. Ch. Muller-Mai, Schmitz, H. J., Strunz, V., Fuhrmann, G., Fritz, Th., and Gross, U. M., J. Biomed. Mater. Res. 23, 1149 (1989).Google Scholar
15.Abe, Y., Kasuga, T., Hosono, H., and de Groot, K., J. Am. Ceram. Soc. 67, C142 (1984).CrossRefGoogle Scholar
16.Kasuga, T., Ichino, A., and Abe, Y., J. Ceram. Soc. Jpn. 100, 1088 (1992).CrossRefGoogle Scholar
17.Ota, Y., Kasuga, T., and Abe, Y., J. Am. Ceram. Soc. 80, 225 (1997).CrossRefGoogle Scholar
18.Nagase, M., Abe, Y., Chigira, M., and Udagawa, E., Biomaterials 13, 172 (1992).CrossRefGoogle Scholar
19.Vogel, J., Wange, P., and Hartmann, P., Glastech. Ber. Glass Sci. Technol. 70, 23 (1997).Google Scholar
20.Alkemper, J. and Fuess, H., J. Non-Cryst. Solids 210, 32 (1997).CrossRefGoogle Scholar
21.Jarcho, M., J. Mater. Sci. 14, 142 (1979).CrossRefGoogle Scholar
22.Niihara, K., Morena, R., and Hasselman, D. P. H., Fracture Mechanics of Ceramics, Vol. 5 (Plenum, New York, 1983), pp. 97–105.CrossRefGoogle Scholar
23.Aoki, H., Medical Application of Hydroxyapatite (IshiyakuEuro-America, Tokyo, Japan, 1994), pp. 25–40.Google Scholar
24.Kokubo, T., J. Non-Cryst. Solids 120, 138 (1990).CrossRefGoogle Scholar
25.Blaskeslee, K. C., Robert, A., and Condrate, A., J. Am. Ceram. Soc. 54, 559 (1971).CrossRefGoogle Scholar