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MoS2/graphene nanocomposite with enlarged interlayer distance as a high performance anode material for lithium-ion battery

Published online by Cambridge University Press:  23 September 2016

Lu Chen ,
Fang Chen ,
Nguyen Tronganh ,
Mengna Lu ,
Yong Jiang ,
Yang Gao ,
Zheng Jiao ,
Lingli Cheng  and
Bing Zhao
Lu Chen
Affiliation:
School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, People's Republic of China
Fang Chen
Affiliation:
School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, People's Republic of China
Nguyen Tronganh
Affiliation:
School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, People's Republic of China
Mengna Lu
Affiliation:
School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, People's Republic of China
Yong Jiang*
Affiliation:
School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, People's Republic of China
Yang Gao
Affiliation:
Shanghai Applied Radiation Institute, Shanghai University, Shanghai 201800, People's Republic of China
Zheng Jiao
Affiliation:
Shanghai Applied Radiation Institute, Shanghai University, Shanghai 201800, People's Republic of China
Lingli Cheng
Affiliation:
Shanghai Applied Radiation Institute, Shanghai University, Shanghai 201800, People's Republic of China
Bing Zhao*
Affiliation:
Shanghai Applied Radiation Institute, Shanghai University, Shanghai 201800, People's Republic of China
*
a) Address all correspondence to these authors. e-mail: [email protected]
b) e-mail: [email protected]
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Abstract

In this article, we report on the preparation of few-layered MoS2/graphene nanocomposite (MoS2/GNS-G) with enlarged interlayer distance as the lithium-ion battery anode via a facile hydrothermal method followed by glucose-assisted thermal annealing. During the synthesis, glucose serving as a small organic molecule can interlay into MoS2 nanosheets, which effectively hinder the aggregation and restacking of MoS2 during the process of heat treatment, retaining a sandwich structure of the composite. The enlarged interlayer distance (approximately 0.98 nm), along with the inserted amorphous carbon, could promote efficient lithium migration into active sites, buffer the volume change and stabilize the electrode structure effectively during the lithium insertion/extraction cycling. Electrochemical tests demonstrate that the MoS2/GNS-G delivers a high discharge capacity of 1583.0 mA h/g in the initial cycle at current density of 100 mA/g. The specific capacity remained at the relative high value of 673.5 mA h/g even at a current density of 1000 mA/g.

Keywords

Energy storagehydrothermalaerogellayeredfreeze drying
Type
Articles
Information
Journal of Materials Research , Volume 31 , Issue 20 , 28 October 2016 , pp. 3151 - 3160
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Copyright
Copyright © Materials Research Society 2016 

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References

REFERENCES

Ramakrishna, H.S., Gomathi, A., Manna, A.K., Late, D.J., Datta, R., Pati, S.K., and Rao, C.N.: MoS2 and WS2 analogues of graphene. Angew. Chem., Int. Ed. 122, 4153 (2010).Google Scholar
Zhu, C., Mu, X., Aken, P.A., Yu, Y., and Maier, J.: Single-layered ultrasmall nanoplates of MoS2 embedded in carbon nanofibers with excellent electrochemical performance for lithium and sodium storage. Angew. Chem., Int. Ed. 53, 2152 (2014).Google Scholar
Smith, R.J., King, P.J., Lotya, M., Wirtz, C., Khan, U., De, S., Neill, A.O., Duesberg, G.S., Grunlan, J.C., Moriarty, G., Chen, J., Wang, J., Minett, A.I., Nicolosi, V., and Coleman, J.N.: Large-scale exfoliation of inorganic layered compounds in aqueous surfactant solutions. Adv. Mater. 23, 3944 (2011).Google Scholar
Novoselov, K.S., Geim, A.K., Morozov, S.V., Jiang, D., Zhang, Y., Dubonos, S.V., Grigorieva, I.V., and Firsov, A.A.: Electric field effect in atomically thin carbon films. Science 306, 666 (2004).Google Scholar
Zeng, Z., Sun, T., Zhu, J., Huang, X., Yin, Z., Lu, G., Fan, Z., Yan, Q., Hng, H.H., and Zhang, H.: An effective method for the fabrication of few-layer-thick inorganic nanosheets. Angew. Chem., Int. Ed. 51, 9052 (2012).Google Scholar
Wang, Z., Ma, L., Chen, W.X., Huang, G.C., Chen, D.Y., Wang, L.B., and Lee, J.Y.: Facile synthesis of MoS2/graphene composites: Effects of different cationic surfactants on microstructures and electrochemical properties of reversible lithium storage. RSC Adv. 3, 21675 (2013).CrossRefGoogle Scholar
Wang, Z., Chen, T., Chen, W.X., Chang, K., Ma, L., Huang, G.C., Chen, D.Y., and Lee, J.Y.: CTAB-assisted synthesis of single-layer MoS2–graphene composites as anode materials of Li-ion batteries. J. Mater. Chem. A 1, 2202 (2013).Google Scholar
Huang, G.C., Chen, T., Chen, W.X., Wang, Z., Chang, K., Ma, L., Huang, F.H., Chen, D.Y., and Lee, J.Y.: Graphene-like MoS2/graphene composites: Cationic surfactant-assisted hydrothermal synthesis and electrochemical reversible storage of lithium. Small 9, 3693 (2013).Google Scholar
Chang, K. and Chen, W.: L-cysteine-assisted synthesis of layered MoS2/graphene composites with excellent electrochemical performances for lithium ion batteries. ACS Nano 5, 4720 (2011).Google Scholar
Hu, L., Ren, Y., Yang, H., and Xu, Q.: Fabrication of 3D hierarchical MoS2/polyaniline and MoS2/C architectures for lithium-ion battery applications. ACS Appl. Mater. Interfaces 6, 14644 (2014).Google Scholar
Lemon, J.P. and Lerner, M.M.: Preparation and characterization of nanocomposites of polyetheres and molybdenum disulfide. Chem. Mater. 6, 207 (1994).Google Scholar
Xiao, J., Choi, D., Cosimbescu, L., Koech, P., Liu, J., and Lemmon, J.P.: Exfoliated MoS2 nanocomposite as an anode material for lithium ion batteries. Chem. Mater. 22, 4522 (2010).CrossRefGoogle Scholar
Kanatzidis, M.G., Bissessur, R., DeGroot, D.C., Schindler, J.L., and Kannewurf, C.R.: New intercalation compounds of conjugated polymers. Encapsulation of polyaniline in molybdenum disulfide. Chem. Mater. 5, 595 (1993).Google Scholar
Zhao, B., Zhang, G., Song, J., Jiang, Y., Zhuang, H., Liu, P., and Fang, T.: Bivalent tin ion assisted reduction for preparing graphene/SnO2 composite with good cyclic performance and lithium storage capacity. Electrochim. Acta 56, 7340 (2011).Google Scholar
Jiang, Y., Ling, X., Cai, X., Jiao, Z., Cheng, L., Bian, L., Nguyen, M., Chu, Y., and Zhao, B.: A novel Fe2O3 rhombohedra/graphene composite as a high stability electrode for lithium-ion batteries. J. Mater. Res. 30, 761 (2015).Google Scholar
Chang, K., Chen, W., Ma, L., Li, H., Li, H., Huang, F., Xu, Z., Zhang, Q., and Lee, J.Y.: Graphene-like MoS2/amorphous carbon composites with high capacity and excellent stability as anode materials for lithium ion batteries. J. Mater. Chem. 21, 6251 (2011).Google Scholar
Ma, L., Huang, G., Chen, W., Wang, Z., Ye, J., Li, H., Chen, D., and Lee, J.Y.: Cationic surfactant-assisted hydrothermal synthesis of few-layer molybdenum disulfide/graphene composites: Microstructure and electrochemical lithium storage. J. Power Sources 264, 262 (2014).CrossRefGoogle Scholar
Li, H.L., Yu, K., Fu, H., Guo, B.J., Lei, X., and Zhu, Z.Q.: MoS2/graphene hybrid nanoflowers with enhanced electrochemical performances as anode for lithium-ion batteries. J. Phys. Chem. C 119, 7959 (2015).Google Scholar
Ji, H., Liu, C., Wang, T., Chen, J., Mao, Z., Zhao, J., Hou, W., and Yang, G.: Porous hybrid composites of few-layer MoS2 nanosheets embedded in a carbon matrix with an excellent supercapacitor electrode performance. Small 11, 6480 (2015).Google Scholar
Ding, S.J., Chen, J.S., and Lou, X.W.: Glucose-assisted growth of MoS2 nanosheets on CNT backbone for improved lithium storage properties. Chem. –Eur. J. 17, 13142 (2011).Google Scholar
Bindumadhavan, K., Srivastava, S.K., and Mahanty, S.: MoS2–MWCNT hybrids as a superior anode in lithium-ion batteries. Chem. Commun. 49, 1823 (2013).CrossRefGoogle ScholarPubMed
Ma, L., Ye, J., Chen, W., Wang, J., Liu, R., and Lee, J.Y.: Synthesis of few-layer MoS2-graphene composites with superior electrochemical lithium-storage performance by an ionic-liquid-mediated hydrothermal route. ChemElectroChem 2, 538 (2015).Google Scholar
Yang, L.C., Wang, S.N., Mao, J.J., Deng, J.W., Gao, Q.S., Tang, Y., and Schmidt, O.G.: Hierarchical MoS2/polyaniline nanowires with excellent electrochemical performance for lithium-ion batteries. Adv. Mater. 25, 1180 (2013).Google Scholar
Xu, X., Fan, Z.Y., Yu, X.Y., Ding, S.J., Yu, D.M., and Lou, X.W.: A nanosheets-on-channel architecture constructed from MoS2 and CMK-3 for high-capacity and long-cycle-life lithium storage. Adv. Energy Mater. 4, 14679 (2014).Google Scholar
Zhao, C.Y., Kong, J.H., Yao, X.Y., Tang, X.S., Dong, Y.L., Phua, S.L., and Lu, X.H.: Thin MoS2 nanoflakes encapsulated in carbon nanofibers as high-performance anodes for lithium-ion batteries. ACS Appl. Mater. Interfaces 6, 6392 (2014).CrossRefGoogle ScholarPubMed
Tronganh, N., Yang, Y., Chen, F., Lu, M., Jiang, Y., Gao, Y., Cheng, L., and Jiao, Z.: SiO2-assisted synthesis of layered MoS2/reduced graphene oxide intercalation composites as high performance anode materials for Li-ion batteries. RSC Adv. 6, 74436 (2016).Google Scholar
Hu, Z., Wang, L.X., Zhang, K., Wang, J.B., Cheng, F.Y., Tao, Z.L., and Chen, J.: MoS2 nanoflowers with expanded interlayers as high-performance anodes for sodium-ion batteries. Angew. Chem., Int. Ed. 53, 12794 (2014).Google Scholar
Jiang, H., Ren, D.Y., Wang, H.F., Hu, Y.J., Guo, S.J., Yuan, H.Y., Hu, P.J., Zhang, L., and Li, C.Z.: 2D monolayer MoS2–carbon interoverlapped superstructure: Engineering ideal atomic interface for lithium ion storage. Adv. Mater. 27, 3687 (2015).Google Scholar
Liu, Q.H., Wu, Z.J., Ma, Z.L., Dou, S., Wu, J.H., Tao, L., Wang, X., Ouyang, C.B., Shen, A.L., and Wang, S.Y.: One-pot synthesis of nitrogen and sulfur Co-doped graphene supported MoS2 as high performance anode materials for lithium-ion batteries. Electrochim. Acta 177, 298 (2015).CrossRefGoogle Scholar
Zhou, J., Qin, J., Zhang, X., Shi, C., Liu, E., Li, J., Zhao, N., and He, C.: 2D space-confined synthesis of few-layer MoS2 anchored on carbon nanosheet for lithium-ion battery anode. ACS Nano 9, 3837 (2015).Google Scholar