Hostname: page-component-cd9895bd7-q99xh Total loading time: 0 Render date: 2024-12-23T13:14:25.513Z Has data issue: false hasContentIssue false
  • English
  • Français

Gas-sensing properties and in situ diffuse-reflectance Fourier-transform infrared spectroscopy study of diethyl ether adsorption and reactions on SnO2/rGO film

Published online by Cambridge University Press:  21 June 2016

Jian Song ,
Kaijin Huang  and
Ning Wang
Jian Song
Affiliation:
State Key Laboratory of Materials Processing and Die & Mould Technology, Huazhong University of Science and Technology, Wuhan 430074, People's Republic of China
Kaijin Huang*
Affiliation:
State Key Laboratory of Materials Processing and Die & Mould Technology, Huazhong University of Science and Technology, Wuhan 430074, People's Republic of China; and State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, People's Republic of China
Ning Wang
Affiliation:
State Key Laboratory of Materials Processing and Die & Mould Technology, Huazhong University of Science and Technology, Wuhan 430074, People's Republic of China
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

Diethyl ether is widely used in the fields of diesel engines, agriculture, food, chemical, biological, pharmaceutical, and medical industries. It is necessary to carry out real-time monitoring of this molecule due to its harmful effects on human health. In this study, a highly sensitive SnO2/rGO gas-sensing material has been prepared by a hydrothermal method. The surface adsorption and reaction processes between the SnO2/rGO gas-sensing film and diethyl ether have been studied by the in situ diffuse-reflectance Fourier-transform infrared spectroscopy at different temperatures. The results show that the SnO2/rGO gas-sensing material has high sensitivity to diethyl ether, and the lowest detection limit can reach 1 ppm, and that ethyl $\left( {{\rm{C}}{{\rm{H}}_{\rm{3}}}\mathop {{\rm{C}}{{\rm{H}}_{\rm{2}}}}\nolimits^ \cdot } \right)$, oxethyl $\left( {{\rm{C}}{{\rm{H}}_{\rm{3}}}{\rm{C}}{{\rm{H}}_2}{{\rm{O}}^ \cdot }} \right)$, ethanol (CH3CH2OH), formaldehyde (HCHO), acetaldehyde (CH3CHO), ethylene (C2H4), H2O, and CO2 surface species are formed during diethyl ether adsorption at different temperatures. A possible mechanism of the reaction process is discussed.

Keywords

gas sensitivitySnO2/rGO filmin situ DIRFTSdiethyl ether
Type
Articles
Information
Journal of Materials Research , Volume 31 , Issue 14 , 28 July 2016 , pp. 2035 - 2045
Check for updates
Copyright
Copyright © Materials Research Society 2016 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

Contributing Editor: José A. Varela

References

REFERENCES

Chen, G.Q., Wu, Y.M., Zhu, T., and Zhang, Y.Z.: Fluorescence spectra of ethyl ether and its characteristic. J. At. Mol. Phys. 24, 101–105 (2007) (in Chinese).Google Scholar
Rakopoulos, D.C., Rakopoulos, C.D., Giakoumis, E.G., and Dimaratos, A.M.: Characteristics of performance and emissions in high-speed direct injection diesel enginefueled with diethyl ether/diesel fuel blends. Energy 43, 214–224 (2012).Google Scholar
Bai, C.H., Zhang, B., Xiu, G.L., Liu, Q.M., and Chen, M.: Deflagration to detonation transition and detonation structure in diethyl ether mist/aluminum dust/air mixtures. Fuel 107, 400–408 (2013).Google Scholar
Yua, X.L., Xie, C.S., Yang, L., and Zhang, S.P.: Highly photoactive sensor based on NiO modified TiO2 porous film for diethyl ether. Sens. Actuators, B 195, 439–445 (2014).Google Scholar
Liu, J.Q., Zhang, Y.T., Yuan, Y.F., and Zuo, W.W.: A nano-Co3O4-based low temperature cataluminescence sensor for the detection of gaseous ethyl ether. Acta Chim. Sin. 71, 102–106 (2013) (in Chinese).CrossRefGoogle Scholar
Cao, X.P.: Ether poisoning death cases. Forensic Sci. Technol. 4, 66–68 (1981) (in Chinese).Google Scholar
Wang, J. and Dong, C.R.: Acute ether poisoning case report. J. Pract. Intern. Med. 3, 252 (1983) (in Chinese).Google Scholar
Scotter, M.J. and Roberts, D.P.T.: Development and validation of a rapid headspace gas chromatography–mass spectrometry method for the determination of diethyl ether and acetone residues in tween extracts of shellfish intended for mouse bioassay for diarrhoetic toxins. J. Chromatogr. A 1157, 386–390 (2007).Google Scholar
Hu, J., Xu, K.L., Jia, Y.Z., Lv, Y., Li, Y.B., and Hou, X.D.: Oxidation of ethyl ether on borate glass: Chemiluminescence, mechanism, and development of a sensitive gas sensor. Anal. Chem. 80, 7964–7969 (2008).CrossRefGoogle ScholarPubMed
Lin, H.B. and Shih, J.S.: Fullerene C60-cryptand coated surface acoustic wave quartz crystal sensor for organic vapors. Sens. Actuators, B 92, 243–254 (2003).Google Scholar
Cao, X.A., Chen, Z.H., and Wang, Y.L.: The determination of ethyl ether vapor in air using cataluminescence on ZnO nano-rods. J. Guangzhou Univ. (Nat. Sci. Ed.), 9, 28–32 (2010) (in Chinese).Google Scholar
Cao, X.A., Wu, W.F., Chen, N., Peng, Y., and Liu, Y.H.: An ether sensor utilizing cataluminescence on nanosized ZnWO4 . Sens. Actuators, B 137, 83–87 (2009).Google Scholar
Volanti, D.P., Felix, A.A., Orlandi, M.O., Whitfield, G., Yang, D.J., Longo, E., Tuller, H.L., and Varela, J.A.: The role of hierarchical morphologies in the superior gas sensing performance of CuO-based chemiresistors. Adv. Funct. Mater. 23, 1759–1766 (2013).Google Scholar
Xie, C.S., Xiao, L.Q., Hu, M.L., Bai, Z.K., Xia, X.P., and Zeng, D.W.: Fabrication and formaldehyde gas-sensing property of ZnO–MnO2 coplanar gas sensor arrays. Sens. Actuators, B 145, 457–463 (2010).Google Scholar
Li, Y., Hsu, P.C., and Chen, S.M.: Multi-functionalized biosensor at WO3–TiO2 modified electrode for photoelectrocatalysis of norepinephrine and riboflavin. Sens. Actuators, B 174, 427–435 (2012).Google Scholar
Yin, L., Chen, D.L., Cui, X., Ge, L.F., Yang, J., Yu, L.L., Zhang, B., Zhang, R., and Shao, G.S.: Normal-pressure microwave rapid synthesis of hierarchical SnO2@rGO nanostructures with superhigh surface areas as high-quality gas-sensing and electrochemical active materials. Nanoscale 6, 13690–13700 (2014).Google Scholar
Chang, Y.H., Yao, Y.F., Wang, B., Luo, H., Li, T.Y., and Zhi, L.J.: Reduced graphene oxide mediated SnO2 nanocrystals for enhanced gas-sensing properties. J. Mater. Sci. Technol. 29, 157–160 (2013).Google Scholar
Lin, Q.Q., Li, Y., and Yang, M.J.: Tin oxide/graphene composite fabricated via a hydrothermal method for gas sensors working at room temperature. Sens. Actuators, B 173, 139–147 (2012).Google Scholar
Wang, P.J., Yao, B.H., Wei, Q.B., Zhang, Y.Q., and Xue, H.F.: The vapor response properties of P(St-AM)@Ag complex microspheres. Chem. Bioeng. 29, 21–25 (2012) (in Chinese).Google Scholar
Ren, Y.F.: Effect of the rare earth elements on semiconductor for gas detector. J. Chin. Rare Earth Soc. 3, 15–19 (1985) (in Chinese).Google Scholar
Slobodian, P., Riha, P., Lengalova, A., Svoboda, P., and Saha, P.: Multi-wall carbon nanotube networks as potential resistive gas sensors for organic vapor detection. Carbon 49, 2499–2507 (2011).CrossRefGoogle Scholar
Ma, X.D., Guo, H.X., Lv, L., He, X., and Feng, X.: Preparation, characterization and gas sensing performance of Ag-supported α-Fe2O3 hybrid. Chem. J. Chin. Univ. 33, 1915–1919 (2012) (in Chinese).Google Scholar
Zhao, W., Zhang, Z.Y., Wu, T.Z., Wang, X.W., Deng, Z.H., and Dai, K.: Preparation of SiC films and study of their response to gases. Electron. Compon. Mater. 24, 36–38 (2005) (in Chinese).Google Scholar
Aizawa, H., Noda, K., Naganawa, R., Yamada, K., Yoshimoto, M., Reddy, S.M., and Kurosawa, S.: Gas sorption of acetone, diethyl ether, toluene, acetic acid, and ammonia on plasma-polymerized hexamethyldisiloxane films coated with quartz crystal microbalance. J. Photopolym. Sci. Technol. 22, 743–745 (2009).Google Scholar
Hummers, W.S. and Offeman, R.E.: Preparation of graphitic oxide. J. Am. Chem. Soc. 80, 1339 (1958).Google Scholar
Zhang, T.R.: The Preparation of Graphene Oxide and Photoluminescence Properties. (Zhejiang Univ., Zhejiang, China, 2013).Google Scholar
Chen, G.S.: The Preparation of SnO2 Nanostructures and Their Optical Properties. (Yangzhou Univ., Yangzhou, China, 2013).Google Scholar
Zhang, H., Feng, J.C., Fei, T., Liu, S., and Zhang, T.: SnO2 nanoparticles-reduced graphene oxide nanocomposites for NO2 sensing at low operating temperature. Sens. Actuators, B 190, 472–478 (2014).Google Scholar
Wang, X.J., Zhang, S.P., and Zhang, G.Z.: A gas-sensing material screening platform for high throughput screening sensor sensitive material. Electron. Technol. 39, 53–56 (2012) (in Chinese).Google Scholar
Zhang, Z.X., Huang, K.J., Yuan, F.L., and Xie, C.S.: Gas-sensing properties and in situ diffuse reflectance infrared Fourier transform spectroscopy study of formaldehyde adsorption and reactions on SnO2 films. J. Mater. Res. 29, 139–147 (2014).Google Scholar
Song, H.J., Zhang, L.C., He, C.L., Qu, Y., Tian, Y.F., and Lv, Y.: Graphene sheets decorated with SnO2 nanoparticles: In situ synthesis and highly efficient materials for cataluminescence gas sensors. J. Mater. Chem. 21, 5972–5977 (2011).Google Scholar
Zhou, Y., Bao, Q., Tang, L.A.L., Zhong, Y., and Loh, K.P.: Hydrothermal dehydration for the green reduction of exfoliated graphene oxide to graphene and demonstration of tunable optical limiting properties. Chem. Mater. 21, 2950–2956 (2009).Google Scholar
Paek, S.M., Yoo, E., and Honma, I.: Enhanced cyclic performance and lithium storage capacity of SnO2/graphene nanoporous electrodes with three-dimensionally delaminated flexible structure. Nano Lett. 9, 72–75 (2009).Google Scholar
Zhang, M., Lei, D.N., Du, Z.F., Yin, X.M., Chen, L.B., Li, Q.H., Wang, Y.G., and Wang, T.H.: Fast synthesis of SnO2/graphene composites by reducing graphene oxide with stannous ions. J. Mater. Chem. 21, 1673–1676 (2011).Google Scholar
Hu, N.T., Yang, Z., Wang, Y.Y., Zhang, L.L., Wang, Y., Huang, X.L., Wei, H., Wei, L.M., and Zhang, Y.F.: Ultrafast and sensitive room temperature NH3 gas sensors based on chemically reduced graphene oxide. Nanotechnology 25, 025502 (2014).Google Scholar
Li, Z.J., Shen, W.Z., Zhang, X., Fang, L.M., and Zu, X.T.: Controllable growth of SnO2 nanoparticles by citric acid assisted hydrothermal process. Colloids Surf., A, 327, 17–20 (2008).Google Scholar
Zhang, H.: Study of Graphene Complex with Metal Oxide SnO2 on Gas Sensing Properties (Jilin Univ., Jilin, China, 2015); pp. 27.Google Scholar
Das, A., Bonu, V., Prasad, A.K., Panda, D., Dhara, S., and Tyagi, A.K.: The role of SnO2 quantum dots in improved CH4 sensing at low temperature. J. Mater. Chem. C 2, 164–171 (2014).Google Scholar
Bonu, V., Das, A., Sivadasan, A.K., Tyagi, A.K., and Dhara, S.: Invoking forbidden modes in SnO2 nanoparticles using tip enhanced Raman spectroscopy. J. Raman Spectrosc. 46, 1037–1040 (2015).Google Scholar
Bonu, V., Das, A., Amirthapandian, S., Dharaa, S., and Tyagia, A.K.: Photoluminescence of oxygen vacancies and hydroxyl group surface functionalized SnO2 nanoparticles. Phys. Chem. Chem. Phys. 17, 9794–9801 (2015).Google Scholar
Lee, S.K., Chang, D., and Kim, S.W.: Gas sensors based on carbon nanoflake/tin oxide composites for ammonia detection. J. Hazard. Mater. 268, 110–114 (2014).Google Scholar
Huang, K.J., Kong, L.C., Yuan, F.L., and Xie, C.S.: In situ diffuse reflectance infrared Fourier transform spectroscopy study of formaldehyde adsorption and reactions on nano γ-Fe2O3 films. Appl. Surf. Sci. 270, 405–410 (2013).Google Scholar
Zhang, Z.Y., Zou, R.J., Song, G.S., Yu, L., Chen, Z.G., and Hu, J.Q.: Highly aligned SnO2 nanorods on graphene sheets for gas sensors. J. Mater. Chem. 21, 17360–17365 (2011).CrossRefGoogle Scholar
Wang, Z.G., Li, P.J., Chen, Y.F., He, J.R., Zheng, B.J., Liu, J.B., and Qi, F.: The green synthesis of reduced graphene oxide by the ethanol-thermal reaction and its electrical properties. Mater. Lett. 116, 416–419 (2014).Google Scholar
Zhang, Z.Y., Zou, R.J., Song, G.S., Yu, L., Chen, Z.G., and Hu, J.Q.: Highly aligned SnO2 nanorods on graphene sheets for gas sensors. J. Mater. Chem. 21, 17360–17365 (2011).Google Scholar
Chang, Y.H., Yao, Y.F., Wang, B., Luo, H., Li, T.Y., and Zhi, L.J.: Reduced graphene oxide mediated SnO2 nanocrystals for enhanced gas-sensing properties. J. Mater. Sci. Technol. 29, 157–160 (2013).CrossRefGoogle Scholar
Hu, J.H. and Zheng, X.F.: Practical Infrared Spectroscopy (Sci. Press, Beijing, China, 2011); pp. 35, 378.Google Scholar
Feng, J.C.: Organic Compound Structure Analysis and Evaluation (National defence Ind. Press, Beijing, China, 2003); pp. 16, 57.Google Scholar
Weng, S.F.: Fourier Transform Infrared Spectrum Analysis (Chem. Ind. Press, Beijing, China, 2010); pp. 377, 388.Google Scholar
Yasunaga, K., Gillespie, F., Simmie, J.M., Curran, H.J., Kuraguchi, Y., Hoshikawa, H., Yamane, M., and Hidaka, Y.: A multiple shock tube and chemical kinetic modeling study of diethyl ether pyrolysis and oxidation. J. Phys. Chem. A 114, 9098–9109 (2010).Google Scholar