Hostname: page-component-cd9895bd7-gbm5v Total loading time: 0 Render date: 2024-12-28T07:37:45.236Z Has data issue: false hasContentIssue false

The effect of surface contamination on thermocapillary flow in a two-dimensional slot

Published online by Cambridge University Press:  20 April 2006

G. M. Homsy
Affiliation:
Department of Chemical Engineering, Stanford University, Stanford, California 94305
E. Meiburg
Affiliation:
Department of Chemical Engineering, Stanford University, Stanford, California 94305 Present address: DFVLR, Göttingen, West Germany.

Abstract

We consider the effect of insoluble surfactants on the steady thermocapillary flow in a differentially heated slot treated previously by Sen & Davis (1982). The equation of state for interfacial tension is taken to be linear in both temperature and surfactant concentration. We treat the problem in the limit of shallow slots and low thermal Marangoni numbers so that the effect of surfactants is described by only two parameters: a surface Péclet number Pe and an elasticity parameter denoted by E, the ratio of the compositional elasticity to the tension difference due to the imposed temperature difference. Using lubrication theory and matched asymptotic expansions, we reduce the problem to a single nonlinear integral–algebraic equation (for the outer core variables), which we solve both numerically and in various asymptotic limits by perturbation theory. It is shown that the general effect of surfactants is to retard the strength of the motion, but that this retardation is not necessarily uniform in space. Surprisingly, there are only extreme cases in which condensed surfactant layers will form, these being E [Lt ] 1, Pe [Gt ] 1. Sharp gradients in surfactant concentrations will not form in the general case of E = O(1). This behaviour is due to the strong coupling between the flow and the interfacial stress, and is contrasted with certain well-known forced-convection problems.

Type
Research Article
Copyright
© 1984 Cambridge University Press

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Adler, J. & Sowerby, L. 1970 J. Fluid Mech. 42, 549.
Berg, J. C. & Acrivos, A. 1965 Chem. Engng Sci. 20, 737.
Chang, C. E. & Wilcox, W. R. 1976 Intl J. Heat Mass Transfer 19, 335.
Clark, P. A. & Wilcox, W. R. 1980 J. Crystal Growth 50, 461.
Davis, R. & Acrivos, A. 1966 Chem. Engng Sci. 21, 681.
Gaines, G. 1966 Insoluble Monolayers at Liquid—Gas Interfaces. Interscience.
Horton, T. J., Fritsch, T. R. & Kinner, R. C. 1965 Can. J. Chem. Engng 43, 143.
Kenning, D. B. R. 1968 Appl. Mech. Rev. 21, 1101.
Levich, V. G. & Krylov, V. S. 1969 Ann. Rev. Fluid Mech. 1, 293.
Merson, R. L. & Quinn, J. A. 1964 AIChE J. 10, 804.
Ostrach, S. 1977 Motion induced by capillarity. In Physiochemical Hydrodynamics: V. G. Levich Festschrift vol. 2, p. 571.
Ostrach, S. 1982 Ann. Rev. Fluid Mech. 14, 313.
Pierson, F. W. & Whitaker, S. 1978 J. Coll. Interface Sci. 63, 129.
Sen, A. & Davis, S. H. 1982 J. Fluid Mech. 121, 163.
Whitaker, S. 1964 Ind. Engng Chem. Fund. 3, 132.
Yih, C.-S. 1968 Phys. Fluids 11, 477.
Yih, C.-S. 1968 Phys. Fluids 12, 1982.