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Intercalation of tris(2,2'-bipyridine)ruthenium(II) into magadiite

Published online by Cambridge University Press:  09 July 2018

M. Ogawa  and
N. Maeda
M. Ogawa
Affiliation:
PRESTO, Japan Science and Technology Corporation Institute of Earth Science, Waseda University, Nishiwaseda 1-6-1, Tokyo 169-50, Japan
N. Maeda
Affiliation:
Institute of Earth Science, Waseda University, Nishiwaseda 1-6-1, Tokyo 169-50, Japan
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Abstract

Intercalation of the tris(2,2'-bipyridine)ruthenium(II) complex cation into a layered silicate (magadiite; the ideal formula for which is Na2Si14O29.nH2O) was investigated. Since the complex cation did not intercalate by a direct ion exchange reaction with the interlayer Na ions in an aqueous medium, dodecyltrimethylammonium exchanged magadiite was used as a precursor. Depending on the loading of the complex cations and the solvents employed for the reactions, two types of tris(2,2'-bipyridine)mthenium(II)-magadiite intercalation compounds formed. One has a basal spacing of ~2.9 nm due to a large amount of the dodecyltrimethylammonium ions which remained in the interlayer space of magadiite and coexisted with the intercalated tris(2,2'- bipyridine)ruthenium(II) complex cations. The other has a basal spacing of '2.0 nm because the intercalated tris(2,2'-bipyridine)ruthenium(II) complex ions form a monolayer in the interlayer space of magadiite.

Type
Research Article
Information
Clay Minerals , Volume 33 , Issue 4 , December 1998 , pp. 643 - 650
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1998

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