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ART. 269 - Does Chemical Transformation influence Weight?

Published online by Cambridge University Press:  05 July 2011

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Summary

Careful experiments by Heydweiller, published in the last number of Drude's Annalen (Vol. v. p. 394), lead their author to the conclusion that in certain cases chemical action is accompanied by a minute, but real, alteration of weight. The chemical actions here involved must be regarded as very mild ones, e.g. the mere dissolution of cupric sulphate in water, or the substitution of iron for copper in that salt.

The evidence for the reality of these changes, which amount to 0·2 or 0·3 mg., and are accordingly well within the powers of a good balance to demonstrate, will need careful scrutiny; but it may not be premature to consider what is involved in the acceptance of it. The first question which arises is—does the mass change as well as the weight? The affirmative answer, although perhaps not absolutely inconsistent with any well ascertained fact, will certainly be admitted with reluctance. The alternative—that mass and weight are not always in proportion—involves the conclusion, in contradiction to Newton, that the length of the seconds' pendulum at a given place depends upon the material of which the bob is composed. Newton's experiment was repeated by Bessel, who tried a number of metals, including gold, silver, lead, iron, zinc, as well as marble and quartz, and whose conclusion was that the length of the seconds' pendulum formed of these materials did not vary by one part in 60,000.

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Publisher: Cambridge University Press
Print publication year: 2009
First published in: 1903

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