Systematic investigations and experience from several application projects on small carbon samples over a number of years have resulted in measuring the radiocarbon content of 10 μg C samples with an overall precision of typically 1%. A substantial reduction of the carbon contamination during graphitization was achieved, resulting in 31±30 ng modern and <100 ng 14C-free carbon. Thus, graphitization is no longer the limiting factor because earlier sample preparation steps usually introduce much larger contamination. The method has been extended to a variety of materials and applied to various projects. Realistic conditions for procedure development can only be achieved in the context of applications on true samples; methods developed are the lyophilization of samples in solution, combustion, ultraviolet oxidation, or carbonate hydrolysis with phosphoric acid, which allows to prepare samples for a wide range of applications. Insights gained from systematic investigations and from real applications are presented.

Soils buried under terrace fills have been widely used to date the construction of ancient agrarian terraces. The reliability of the obtained radiocarbon dates entirely depends on the degree of preservation and isolation of the Ab horizons and on the amount of embedded older carbon. To assess these caveats, we analyzed 14 14C dates (11 on charred material and 3 on the bulk organic fraction) obtained from buried soils under Andalusi terrace fills in Ricote, Spain (AD 711–1492). The preservation of Ab horizons was assessed through bulk analyses [particle size distribution (PSD), carbon analyses, magnetic susceptibility (Mag Sus)] and statistics [Welch’s ANOVA, MANOVA (Wilk’s lambda) and effect size tests]. The effects of older carbon were quantified through the systematic dating of Ab horizons within the earliest terrace cluster of Ricote. Our results show that (1) Ab horizons were not disturbed nor mixed with the terrace fills above; (2) the dates determined from the bulk organic fraction were statistically significantly older than those provided by the charred material, probably due to the higher stability of the microcharcoal fraction; and (3) the earliest dates measured on charcoal clustered reliably around cal AD 989–1210, suggesting that the first Andalusi irrigated terraces of Ricote were built between the end of the 10th and the beginning of the 13th centuries AD.

The Harwell system for measuring milligram size samples using Brookhaven miniature gas counters is fully operative. It comprises 12 counters of different sizes which operate simultaneously within a single NaI crystal (300mm diameter × 300mm long) acting as an anti-coincidence guard counter. Brief details are given of the construction and commissioning of the system, including counter assembly, shield design, electronics, data capture, data analysis, and chemical processing and filling procedures. The performance of the system and an overall view of the fields of application for which the counters have important applications are discussed.

When constructing absolute chronologies in archaeology, the aim is to detect archaeological events. In this respect, we draw attention to the relation between the radiocarbon ages of human bone collagen samples and the absolute dating evidence on the age at death. In recent material, Mebus Geyh (2001a,b) described the offset between the former and the latter, and suggested the relevant correction. The corrected 14C ages pertain to the age of the individual at death.

We have developed an application of Geyh's original observation, which we term the human bone collagen offset (HBCO) correction, to apply to archaeological 14C dates. If the death and interment of individuals are identical, the corrected 14C date reliably informs us about the deposition of the body and accompanying grave goods. In archaeology, the concrete correction value is determined by the anthropologically estimated age of the individual, which we model by a normal (Gaussian) distribution. The eventual impact of the HBCO correction on archaeological chronology depends on the portion of the calibration curve through which the HBCO-corrected date is calibrated. At a certain level of 14C measurement precision, the difference between the HBCO-corrected and non-corrected calendar dates can be considerable.

This paper discusses the comparative chronology of Upper Paleolithic sites in the Middle Dnieper River basin, based on archaeological and radiocarbon evidence. Three chronological periods of the development of the Upper Paleolithic are distinguished in this area. According to the data obtained, the third period is similar to the European Magdalenian, yet its economies were different. The base of the subsistence economy for Dnieperian hunters was the procurement of mammoth, while reindeer was the most important for the subsistence of European Magdalenian. The abundance of mammoths and the raw material in the form of mammoth tusks made a deep impact on both the economy and material culture of the hunters in the Dnieper River basin. The 14C dates confirm the chronological subdivision.

The determination of the age of tropical trees and palms is of significant importance for ecological studies and designing sustainable forest management plans. Radiocarbon is a powerful tool that can potentially help the determination of ages and growth rates of these plants. However, the application of 14C analyses has one important problem for trees without annual rings and palms: the calibration of 14C measurements with common programs such as CALIBomb or OxCal gives erroneous determinations for wood formed between AD 1954 and 1964. This problem is illustrated here using samples from a tropical tree (Otoba gracilipes) and a tropical palm (Oenocarpus bataua). This study shows how the use of two adjacent samples can help to unambiguously determine the real age of the samples and their mean growth rates. For comparison, long-term growth measurements for both species were used and it was determined that 14C analyses provide accurate determination of growth rates for tropical trees and palms. Furthermore, the application of 14C analyses in palms allows the determination of the rosette stage, rarely quantified in forest inventories and life-history studies.

The following is a list of dates obtained since the time of the compilation of List X in December 1964. The method is essentially the same as that used for the work described in the previous list. Two CO2-CS2 Geiger counter systems are used. The equipment and counting techniques have been described elsewhere (Crane, 1961). The dates and estimates of error in this list follow the practice recommended by the International Radiocarbon Dating Conferences of 1962 and 1965, in that (a) dates are computed on the basis of the Libby half-life, 5570 yr, (b) A.D. 1950 is used as the zero of the age scale, and (c) the errors quoted are the standard deviations obtained from the numbers of counts only. In previous Michigan date lists up to and including VII we have quoted errors at least twice as great as the statistical errors of counting, in order to take account of other errors in the over-all process. If the reader wishes to obtain a standard deviation figure which will allow ample room for the many sources of error in the dating process, we suggest he double the figures that are given in this list.

The following list contains samples of geologic interest that were processed from June 1980 through March 1983 at the Illinois State Geological Survey (ISGS) Radiocarbon Dating Laboratory. The benzene liquid scintillation technique was used following laboratory procedures previously reported by Coleman (1973, 1974).

Radiocarbon was measured in dissolved inorganic carbon (DIC) and living organisms collected off the west coast of Baja California in October 1980. Samples from three locations were examined. Δ14C of DIC at the southernmost station was higher than those further north, which reflects reduced upwelling in the southern region. Crabs and anchovies had Δ14C values significantly lower than surface DIC Δ14C, indicating the incorporation of ‘older', sediment-derived carbon sources from their diets. Comparisons are made between our DIC Δ14C measurements and those obtained during other cruises and at a coastal site, from 1959 through 1987. Two distinct time histories of DIC Δ14C are apparent for the post-bomb period: 1) a lower Δ14C curve for sites close to the coast influenced by enhanced coastal upwelling; and 2) a higher Δ14C curve for sites further offshore within the California Current.

Several authors have claimed that radiocarbon dates in the Ancient Near East are too early. Herein, a hypothesis that might explain this is presented. Marine degassing of “old” carbon (i.e. 14C-deficient C), induced by upwelling of old subsurface water, has been observed, in modern times, to cause century-scale 14C ages in the surface atmosphere. A review of the Mediterranean Sea post-ice-age circulation concludes that the subsurface waters became very old, primarily due to millennia-long stagnation. It is hypothesized that as the stagnation ended, subsurface waters were brought towards the surface, where they degassed old carbon. Additionally, Anatolian dendrochronology is shown to not contradict the hypothesis.

We studied the chronology and periodization of the Pit-Grave (Yamnaya) culture at the Volga and Ural interfluve. Establishing the chronology of the Pit-Grave culture by archaeological methods is difficult due to the lack of artifacts in the burials. Therefore, we excavated 3 kurgan groups in the Orenburg region of Russia during the last decade. Eighteen kurgans of the Pit-Grave culture were studied using archaeological and paleopedological methods and radiocarbon dating. The funeral complexes studied were divided into 3 stages. A variety of carbon-containing materials from the same complexes were dated by different laboratories to increase the accuracy of the obtained dates. In addition, from the excavations of the last years some monuments of the Repino stage, the earliest period of the Pit-Grave culture, were dated using ceramics. Together with archaeological and paleopedological data, 14C dating helped to clarify and, in general, to confirm the 3-stage periodization of the Pit-Grave culture in the Volga-Ural interfluve: the early (Repino) stage, 4000–3300 BC; the advanced (classical) stage, 3300–2600 BC, which is divided into substages A and B at 3300–2900 and 2900–2600 BC, respectively; and the late (Poltavkinsky) stage, 2600–2300 BC.

We have undertaken extensive programs of natural radiocarbon measurement to date the evidence for various events buried in peat bogs. Two case studies are described here: 1) the chronological reconstruction of South Kamchatka volcanic eruptions and, 2) investigation of multi-layered archeological sites in the Upper Volga River Basin. Studies of sample composition and peat taphonomy allowed us to determine the source of 14C age deviations and to reconstruct the environmental history of organic matter accumulation. Data sets, obtained from different types of peat bog and containing traces of these Holocene events, are discussed.

Radiocarbon (14C) activity in groundwater can be used to determine subsurface residence time up to ∼40 kyr, providing crucial information on dynamic properties of groundwater and on paleoclimate. However, commonly applied sampling methods for dissolved inorganic carbon (DIC-14C) are prone to low level of modern atmospheric contamination, resulting in underestimation of groundwater ages that cluster around 30–40 kyr. We extract CO2 gas from groundwater using a device originally developed for studies of noble gas radionuclides. Carbon is collected in the gas phase, eliminating the possibility of fostering microbial activities and aqueous chemical reactions during sample storage. This method collects CO2-14C and radiokrypton (81Kr and 85Kr) samples simultaneously. The presence of any shorter-lived 85Kr is used to evaluate the degree of atmospheric contamination during sampling or mixing of young groundwater. Most groundwater samples showed lower CO2-14C activities than those of DIC-14C, presumably due to the absence of atmospheric contamination. Samples with 81Kr age exceeding 150 kyr have no detectable CO2-14C except where mixing sources of young groundwater is suspected. These field data serve as confirmations for the reliability of the newly presented sample collection and CO2-14C method, and for the outstanding roles of radiokrypton isotopes in characterizing old groundwater.

The Florence Radiocarbon Dating Laboratory was built in 1970 under the direction of Consiglio Nazionale delle Ricerche at the Istituto di Antropologia, Università di Firenze.

A newly operating accelerator mass spectrometry (AMS) facility such as VERA has to go through an extensive testing phase in order to establish optimal conditions for 14C measurements, especially in the field of archaeological samples where an overall precision of 0.5% is desirable.

We discuss the results of our measurements at the milligram carbon level as they relate to long-term stability, reproducibility, precision and isotope fractionation.

Amino acid composition data and stable isotope ratios (14N, D, and13C) are being evaluated as sources of information to indicate the presence of non-indigenous organics in bone samples intended for 14C analyses. The study is being conducted in the context of the planned measurement of Pleistocene bone samples by a high energy mass spectrometric 14C detection system.

The dating equipment and operating conditions remain essentially as previously described. All samples in this list have been counted at a filling pressure equivalent to 152 cm Hg at 20°C. The proportional counter has recently been re-wired, resulting in a lowering of the operating voltage. Electron-microscopic examination of the old counter wire showed considerable thickening due to the accumulation of fine dust particles. A filter is being installed in the filling line to minimize this effect. Pretreatments are as given in previous date lists unless otherwise stated.

The radiologic impact of 14C produced by the nuclear fuel cycle is assessed at both global and local levels. In the former context, it is predicted here that the specific activity of atmospheric CO2 in the year 2050 will be ca 7.6 pCig-1 C. Although this is similar to the present level, the subsequent collective dose commitment could be highly significant.

The enhancement of 14C concentrations around the nuclear fuel-reprocessing plant at Sellafield (Windscale) in Cumbria, U K has been monitored over recent years. For example, maximum levels of 27.2 pCig-1C (∼350% above natural) during 1984 were observed < 1 km from the plant, with enhanced activities detectable to at least 29km. Nevertheless, it is clear that the radiologic significance to the local population is low. The spatial distribution of the excess 14C allows atmospheric dispersion models to be tested in the context of continuous releases and the results thus far show that the Gaussian plume model performs successfully.

The Balearic quicklime burials of the Iron Age have been radiocarbon dated. Because the bones found are unsuitable for dating, lime was dated using the titration method, with results indicating that in some samples there is still fossil limestone carbonate present, while other samples suffered from recarbonation. Nevertheless, 14C dates on lime and organic matter agree when both arc present. The titration method allows calculating a consensus value.

Measurements of the stable isotope ratio 13C/12C, relative to PDB, were made for fractionation correction purposes on all oak samples used in the Irish oak 14C calibration curve. Stable isotope data have not been published previously. We have collated the stable isotope data from the calibration work, carried out some further measurements to investigate anomalies in the original results, and generated tables of data that include site and tree information pertaining to both stable isotopes and source material for 14C calibration measurements. The data suggest that land-grown trees tend to be isotopically lighter than bog-grown wood, and that the Irish trees used in the calibration exercise tend to be isotopically heavier than those from Scotland and England. Preliminary analysis of the data is given.