Archaeologists interested in radiocarbon dating shell midden sites express concern regarding the accuracy of shell dates and how such determinations should be interpreted. This article discusses the problem of dating shells from sites in the southeastern United States. New results are presented comparing shell, bone, and soil-charcoal age determinations from the Crystal River site, located along the west-central Gulf Coast of Florida. Crystal River is a large multimound site whose occupants engaged in long-distance exchange throughout eastern North America during the Woodland period (∼1000 BC to AD 1050). In the summer of 2012, test units were excavated in several contexts at the site, including both mounds and occupation areas. Samples were collected for 14C dating, which were then processed at the University of Georgia Center for Applied Isotope Studies. This article focuses on samples from the stratified shell midden, from which it was hoped to construct a local correction for marine shell that could be used to date other contexts. The soil-charcoal and bone collagen from these samples have very similar ages (bone samples ranging from about 100 cal BC to cal AD 530 and soil-charcoal from cal AD 345 to 560); however, the shell samples collected from the same stratigraphic units are significantly older than the terrestrial dates (ranging from 1300 to 390 cal BC). The difference in calibrated ages between organic materials and the shells ranges between 560 to 1140 yr. This phenomenon cannot be explained solely by the marine reservoir effect. It appears that all the shell samples formed in mixed marine (∼50–60%) contexts, as indicated by the stable isotope ratios and the amount of atmospheric carbon remaining in the samples. The age of the shell samples cannot be used to date archaeological events as they are influenced not only by the marine reservoir effect, but also the local hardwater effect, which makes them significantly older.

The density (BSG) of bone increases, at the osteon scale, during lifetime aging within the bone. In addition, post-mortem diagenetic change due to microbial attack produces denser bioapatite. Thus, fractionation of finely powdered bone on the basis of density should not only enable younger and older populations of osteons to be separated but also make it possible to separate out a less diagenetically altered component. We show that the density fractionation method can be used as a tool to investigate the isotopic history within an individual's lifetime, both in recent and archaeological contexts, and we use the bomb 14C atmospheric pulse for validating the method.

Local reservoir ages are often estimated from the difference between the radiocarbon ages of aquatic material and associated terrestrial samples for which no reservoir effect is expected. Frequently, the selected aquatic material consists of bivalve shells that are typically well preserved in the archaeological record. For instance, large shell middens attest to the importance of mussel consumption at both coastal and inland sites. However, different physiological mechanisms associated with tissue and shell growth may result in differences in reservoir effects between the surviving component (shell) and the component relevant to dietary reservoir effects in consumers (tissue). The current study examines bivalve tissue-shell age differences both from freshwater and marine contexts close to archaeological sites where human consumption of mollusks has been attested. Results exhibited significant 14C age differences between bivalve tissue and shell in a freshwater context. In a marine context, no significant bivalve tissue-shell age differences were observed. The results also showed that riverine and lacustrine shells show large and variable freshwater reservoir effects. The results have important implications for establishing local reservoir effects especially in a freshwater environment. For good a priori knowledge of expected 14C differences in organic and inorganic water, carbon is thus necessary. Furthermore, the high variability in freshwater shell 14C ages implies the need for representative sampling from the archaeological record.

Ash is formed when plant calcium oxalate crystals (CaC2O4) decompose to form calcite (CaCO3). We found that ash does retain the original calcium oxalate radiocarbon concentration, but in addition, there is another minor 14C source. This is shown by the presence of a consistent small shift in the pMC and δ13C levels when comparing cellulose and ash from modern and archaeological woods. Possible mechanisms for 14C exchange during combustion or due to diagenesis are considered in order to define parameters for identifying better-preserved wood ash samples.

The following is a list of radiocarbon dates obtained since the preparation of the manuscript for the publication of Michigan V, in December, 1959. The method of measurement and treatment of data are the same as those described in the introductions to Michigan lists III and IV. A full statement on the Michigan counter is referred to by Crane (p. 46) in this issue.

We have measured 14C, 210Pb and 137Cs profiles in two representative cores from Manasbal Lake, Kashmir, India. The sedimentation rate derived from 210Pb and 137Cs in the upper part of the core is in the range of 3.4 to 5.5 mm yr−1. In contrast, 14C ages show an inversion at depths >20 cm. These results are attributed to the erosion of the ubiquitous 10–20-m-thick loess mantle, based on the similarity of 14C ages of the inversion layer in the sediments and the paleosols present in the catchment area. Frequency-dependent mineral magnetic susceptibility (χfd), carbon to nitrogen ratios and pigment concentrations in the profile show a significant amount of allochthonous component in the lake deposits and support the conclusion that the 14C dates do not reflect the chronology of the in-situ lake sedimentation but episodic deposition of the surrounding loess. Thus, 14C serves as a useful tracer to understand source components of the sediments.

Radiocarbon dating by accelerator mass spectrometry (AMS) of the shell bar section of Qaidam Basin, NE Tibetan Plateau, shows that this section was formed between ~39.7 and ~17.5 14C kyr BP and represented the highest paleolake development period since the Late Pleistocene. It was difficult to obtain reliable dates due to the low organic carbon content, which was formed mainly by authochtonous algae-bacteria (Zhang et al. 2007a). In order to improve the dating, 14C ages of both the alkali residual and acid-soluble components of the organic carbon were measured to check the consistency of the dating results. Total organic carbon (TOC) content and stable carbon isotopes (δ13Corg) might also be used as critical references for checking the reliability of dates. For example, in our study of the shell bar section from Qaidam Basin, we found that when the TOC content was higher than 0.15% and/or δ13Corg was lower than −23, the AMS dates were reliable. AMS dating of fossil shells demonstrated that they could provide valuable age information. The ages given by fossil shells are comparable to those of bulk carbonate from a similar sampling site, and are about 15~18 kyr older than the ages given by organic matter. Due to the U/Th dating requirements and open nature of the system, we concluded that U/Th dating results are unreliable and that this technique is unsuitable for dating halite deposits from Qaidam Basin.

The Chronos 14Carbon-Cycle Facility is a new radiocarbon laboratory at the University of New South Wales, Australia. Built around an Ionplus 200 kV MIni-CArbon DAting System (MICADAS) Accelerator Mass Spectrometer (AMS) installed in October 2019, the facility was established to address major challenges in the Earth, Environmental and Archaeological sciences. Here we report an overview of the Chronos facility, the pretreatment methods currently employed (bones, carbonates, peat, pollen, charcoal, and wood) and results of radiocarbon and stable isotope measurements undertaken on a wide range of sample types. Measurements on international standards, known-age and blank samples demonstrate the facility is capable of measuring 14C samples from the Anthropocene back to nearly 50,000 years ago. Future work will focus on improving our understanding of the Earth system and managing resources in a future warmer world.

This list includes most of the samples measured during 1974 and most of those measured previously but not published in the preceding date list (R, 1975, v 17, p 4–34.)

Results of measurements for 3 years (1981–1983) of 14C activity of dissolved inorganic carbon (DIG) in water samples from the Korana River, as well as that of recent tufa and aquatic plants, showed that 14C concentration increases from karst spring to the estuary. A model describing the increase of 14C activity was developed assuming that the increase is due to the exchange of the dissolved CO2 in stream water with atmospheric CO2 and to dissolution of CO2 from the decay of organic material and root respiration. It is possible to distinguish these two contributions by measuring the δ13C values of DIC in water. As expected, our data show that the exchange process between atmospheric CO2 and DIC dominates at rapids and waterfalls, while biologic contribution is much higher in lakes and along the lowland flow of the Korana River. Agreement between the calculated and the measured activities supports the proposed mechanisms of chemical and isotopic exchanges in stream waters.

The usefulness of radiocarbon dates in archaeology greatly depends on both the stratigraphic relationship of the sample submitted and on the origin and homogeneity of the measured carbon. For very small samples, stratigraphic relationships can raise additional problems of movement. In chemically well-characterized materials, the best example being collagen, the carbon source can be reasonably well purified. Many samples, however, survive as a complex mixture of high molecular weight polyphenolic materials, with properties between charcoals, humic acids, and lignins. Charred bone, eg, which rarely contains useful quantities of amino acids, and charred seeds, as well as ‘charcoal,’ frequently come into this category. For such samples, the likelihood of contamination by percolating soil humics is high. It is often possible to extract chemically different fractions and to compare the dates obtained. A less exact comparison can also be made for different samples from the same context. The results suggest that ‘humic’ acid dates can be reliable in a surprisingly frequent number of situations, and that where direct comparison is possible, the reliability can be individually assessed.

Radiocarbon concentration measurements in tree rings from Upper Silesia indicate significantly lower 14C concentration as compared to the concentrations occurring in “clean air” areas. This phenomenon is known as the Suess effect and is caused by contamination with inactive carbon that originates from fossil fuels combustion. This effect is observed in large urban and industrial areas. Samples for the measurements presented in the paper were collected in some of the largest cities in Upper Silesia: Gliwice, Ruda Śląska, and Chorzów. The samples were annual tree rings (Populus nigra, Pinus silvestris) covering years 1965–1992 and the atmospheric CO2 collected weekly between December 1994 and December 1995.

Increasing concern with nuclear waste isolation technology is leading to additional studies of naturally occurring isotopes in ground water. Such studies provide information on 1) the use of radionuclides to estimate ground-water travel times and/or residence times. This information can he an extremely useful adjunct to conventional hydrologic data in developing the understanding of regional hydrology needed in the site selection process, and 2) the use of natural radionuclides as analogues to the behavior of radionuclides of concern in nuclear waste.

14C is one of the radionuclides that are produced to different degrees by neutron-induced reactions in all types of nuclear reactors. Part of the 14C created is continuously released into the surrounding environment during normal operation as airborne effluents in various chemical forms (such as CO2, CO and hydrocarbons) through the ventilation system of the plant. Because of the biological importance of carbon and the long half-life of 14C, it is of interest to measure the releases and their incorporation into living material. We report here on the 14C activity concentrations in annual tree rings and the air around two Swedish nuclear power plants, as well as the background 14C activity levels from two reference sites in southern Sweden from 1973–1996. We used both accelerator mass spectrometry (AMS) and decay counting in the investigation.

Microarchaeological methods, especially those focused on geoarchaeology and radiocarbon dating, have revolutionized the manner in which the Iron Age settlement peak in the Negev Highlands is interpreted. We review here results from field and laboratory studies conducted at two Iron Age sites (Atar Haroa and Nahal Boqer) compared to one Byzantine/Early Islamic site (Wadi el-Mustayer)—all located near Sede Boqer. We present our methodology, which is based on small-scale but detailed excavations, study of sediments, and identification of livestock dung remains and their utility as indicators of past subsistence practices. To this we add meticulous 14C dating, ceramic petrography, and identification of botanic and zoological remains. We conclude that subsistence during the Iron Age included tending livestock but did not include agriculture. We further propose that the long-distance trade of copper from the Arabah Valley under Egyptian auspices and possibly the trading of cinnamon, dates, and other Arabian/Indian commodities were the driving force in the initiation (and later decline) of the Iron Age settlement system. We hypothesize that the agricultural settlement peak during the Byzantine/Early Islamic period was also influenced by an imperial power from outside of the Negev and that large-scale agriculture was enabled due to the adoption of new agricultural techniques, including terracing of ephemeral streams along with water diversion systems and possibly water storage facilities such as advanced cisterns. Future studies are expected to shed additional light on the complexity of settlement oscillations in the Negev Highlands region in key periods such as the Early and Intermediate Bronze Ages.

Four charcoal samples from loess key sites in Austria, Moravia, and western Ukraine were submitted to ABOx (acid-base oxidation) pretreatment to compare results with the classical ABA (acid-base-acid) method. For this purpose, charcoal samples already dated in Groningen laboratory were selected from 3 archaeological sites: Molodova V in western Ukraine (subunit 10–1, ∼32.6 ka BP), Willendorf II in Austria (unit C4, ∼32.1 ka BP and unit C8, ∼38.9 ka BP) and Vedrovice V in Moravia (unit 4, upper part of Bohunice soil, ∼39.5 ka BP). Each selected charcoal sample has been homogenized and divided into 3 subsamples, which were submitted to ABA in Groningen and to ABA and ABOx pretreatments in Oxford. The results show that the ABOx dates are older than the ABA dates. Nevertheless, down to ∼40 ka BP ABOx and Groningen ABA dates appear in good agreement within a time interval of ∼1 millennium at 1σ. However, Groningen ABA pretreatment produces older dates than the Oxford ABA pretreatment. Both Oxford ABOx and Groningen ABA pretreatments provide sets of dates in good agreement with the chronological background of each selected site.

The Rehovot Radiocarbon Laboratory was established in 1968, as an extension of a low-level tritium laboratory, which has been in operation many years. Intended to be a supporting facility in geohydrological studies, the laboratory now offers general services in carbon dating.

The main force driving technical development of the radiocarbon dating technique is the wide spectrum of applications that cross interdisciplinary boundaries of Earth and social sciences. This paper provides a very brief overview of some of the many applications of 14C analysis to various studies of human origin and migration, cultures and history, past and present environment, and the human body itself.

The following list comprises a selected number of measurements made up to November, 1965. Age calculations are based on a contemporary value equal to 95% of the activity of the NBS oxalic-acid standard, and on a half life for C14 of 5570 yr. Results are reported in years before 1950, and in the A.D./B.C. scale. Errors quoted include the standard deviations of the count rates for the unknown sample, the contemporary value, and the background. Because possible errors arising from isotopic fractionation in the plants, or from the de Vries effect, have not been included, calculated errors smaller than 100 yr have been increased by rounding to that figure as a minimum.

This work presents an attempt to date brines and determine flow rates of hypersaline groundwater in the extremely dynamic system of the Dead Sea (DS), whose level has dropped in the last 30 yr by ∼20 m. The processes that affect the carbon species and isotopes of the groundwater in the DS area were quantified in order to estimate their flow rate based on radiocarbon and tritium methods. In contrast to the conservative behavior of most ions in the groundwater, the carbon system parameters indicate additional processes. The dissolved inorganic carbon (DIC) content of most saline groundwater is close to that of the DS, but its stable isotopic composition (δ13CDIC) is much lower. The chemical composition and carbon isotope mass balance suggest that the low δ13CDIC of the saline groundwater is a result of anaerobic organic matter oxidation by bacterial sulfate reduction (BSR) and methane oxidation. The radiocarbon content (14CDIC) of the saline groundwater ranged from 86 pMC (greater than the ∼82 pMC value of the DS in the 2000s) to as low as 14 pMC. The similarity between the 14CDIC value and Na/Cl ratio of the groundwater at the DS shore and that of the 1980s DS brine indicates that the DS penetrated to the aquifer at that time. The low 14CDIC values in some of the saline groundwater suggest the existence of ancient brine in the subaquifer.