Although soil contains about three times the amount of carbon present in the preindustrial atmosphere, determining how perturbations (e.g., changing land use, CO2 fertilization, changing climate and anthropogenic nitrogen deposition) alter soil carbon storage and influence atmospheric CO2 levels has proved elusive. Not knowing the soil carbon turnover times causes part of this uncertainty. I outline a strategy for using radiocarbon measurements to estimate soil organic matter turnover times and inventories in native soil. The resulting estimates of carbon exchange produce reasonable agreement with measurements of CO2 fluxes from soil. Furthermore, derivatives of the model are used to explore soil carbon dynamics of cultivated and recovering soil. Because the models can reproduce observed soil 14C measurements in native, cultivated, and recovering ecosystems (i.e., the underlying assumptions appear reasonable), the native model was modified to estimate the potential rate of additional carbon storage because of CO2 fertilization. This process may account for 45–65% of the “missing CO2 sink.”

The Earth is within the Contemporaneous Solar Maximum (CSM), analogous to the Medieval Solar Maximum (MSM). If this analogy is valid, solar activity will continue to increase well into the 21st century. We have completed 75 single-ring and 10 double-ring measurements from ad 1065 to ad 1150 to obtain information about solar activity during this postulated analog to solar activity during the MSM. δ14C decreases steadily during the period ad 1065 to ad 1150 but with cyclical oscillations around the decreasing trend. These oscillations can be successfully modeled by four cycles. These four frequencies are 1/52 yr-1, 1/22 yr-1, 1/11 yr-1, and 1/5.5 yr, i.e., the 4th harmonic of the Suess cycle, the Hale and Schwabe cycles and the 2nd harmonic of the Schwabe cycle.

A representative selection of Roman and Coptic textiles is used to compare the radiocarbon dating results with the chronology proposed by art historians. In some cases, the comparison was made on individual objects, but in other cases, groups of stylistically and/or technologically related textiles were compared. In the case of the latter, the interquartile range was calculated. The results of this comparison show that some individual samples and groups are dated older than expected, while for another group the opposite is the case. One group was matching well with the presumed period as a whole, but not on the basis of the individual pieces. The analyses showed the necessity of 14C dating to obtain a more accurate dating of Coptic textiles.

The purpose of this paper is to analyze the numerous holocene subfossil trees (Pinus silvestris) buried in alluvial deposits in the Southern French Alps. These trees lived between the Allerød and Subboreal periods, according to 14C dates. Our dendochronological studies explain the trees' sudden death as due to morphological crisis brought on by climatic oscillations. Tree-ring series could be used to identify the variability of early Holocene atmospheric 14C levels.

This paper presents a synthetic approach to 14C dating of calcareous tufa, based on statistical analysis of correlations betwen lithologic type of tufaceous sediment, carbon isotope composition, and apparent age. Experimental data on several profiles from southern Poland and the United Kingdom reveal either constant or systematically changing values of apparent age. Constant value of apparent age in a profile can be attributed to calcareous muds precipitated from stagnant or low-energy water, and to tufas precipitated from turbulent water (oncoids, stromatolites, moss travertines) which are characterized by lack of significant correlation between δ 13C and 14C age of tufa carbonate. It was found that the relation between the apparent age of tufaceous sediment and δ 13C value of tufa carbonate depends on lithologic type of tufa. Phenomenological equations describing the dependence of apparent age upon δ 13C are given, and applied to estimate true ages of tufas from Gliczarów (southern Poland) and Folkestone (United Kingdom).

In this paper we analyze the radiocarbon (14C) concentration changes over the whole operational period of the Ignalina Nuclear Power Plant (INPP) including the post-shutdown decommissioning. Environmental samples from the vicinity of the INPP and a rural area as background of pine tree rings were analyzed with the single stage accelerator mass spectrometer (SSAMS). The analysis shows the local influence of the INPP from 3 to 7 pMC. The whole time span from 1983 to 2015 is divided into three periods representing the early and late operational and post-shutdown stages of the INPP with different 14C profiles in analyzed samples. The influence of the maintenance of the INPP and radioactive waste management activities are indicated and discussed.

Radiocarbon measurements in seawater samples taken at six stations in the southwestern North Pacific visited during the International Atomic Energy Agency (IAEA) 1997 Pacific Ocean Expedition were carried out at the accelerator mass spectrometry (AMS) facility of the Japan Atomic Energy Research Institute (JAERI). Three stations were located close to GEOSECS stations, and three were in the vicinity of Bikini and Enewetak Atolls, which may be influenced by former nuclear weapons testing. Compared with the GEOSECS data (1973), our results show an increase of 14C in intermediate waters. Furthermore, it is estimated that bomb-produced 14C inventories in the water column have increased by more than 20% during the last 24 years. However, vertical profiles of Δ14C at the stations near Bikini and Enewetak Atolls show a similar general trend to those found in other stations.

The Natufian culture of the southern Levant played an integral role in the transition from simple huntergatherers to food-producing societies of the Neolithic, but the major Natufian hamlets are currently poorly dated. Moreover, none of these complex, continuously occupied base camps have delivered an adequate number of dates to enable an in-depth delineation of intra-Natufian developments. This paper presents the first results of our dating program at el-Wad terrace, Mount Carmel (Israel), one of the major Natufian hamlets of the “core area” of this culture. Thirteen accelerator mass spectrometry (AMS) radiocarbon age determinations were obtained from 46 bone (both ungulate and human) and charcoal samples, originating in Early Natufian living surfaces, dwellings, and burials. The obtained dates are largely in agreement with the cultural affiliation of the samples (13–15 kyr cal BP). Two series of dates from different locations show good agreement with the stratigraphy. The ages of the burials clearly point to their being younger than the living surfaces seemingly associated with them. Presently, no burials may be linked with the major architectural phase of Early Natufian el-Wad. Our ongoing dating program and the processing of additional samples from refined contexts will help shed important light on the initial phases of the Natufian culture, habitation duration, intensity, and continuity, as well as the relationships between site features and stratigraphy.

The following list consists entirely of dates for archaeologic samples from the British Isles measured since about mid-1970 up to June 1974*. The dates were obtained by liquid scintillation counting of benzene using a Model 3315 Packard Tricarb Liquid Scintillation Spectrometer. In general, procedures are as described in the previous date list (R, 1971, v 13, p 157; see also Burleigh, 1972). However, data processing was improved by means of a real-time link with a Hewlett Packard 2100A computer having 32K of core, which accepts readings from the counter at the end of each individual counting period. The computer monitors the accumulated sample counts and reports when the statistical error terms of these have reached previously chosen limits; final dates are then obtained on supplying the appropriate benzene sample weights and isotopic fractionation values. The system maintains a permanent record of all the data obtained from measurement of samples and reference standards and gives warning of any serious changes in counter performance. A full description of the capabilities of this system is given elsewhere (Hall and Hewson, in press). Finally, improvements were made to the bomb used for initial combustion of sample materials (Burleigh, 1974) and a new, stainless-steel, lithium reaction furnace (similar to that described by Polach and Stipp, 1967) was recently installed.

We measured radiocarbon ages of 22 decadal replications and 1 bulk group from 5 tree-ring specimens using acid-base-acid pretreatment and accelerator mass spectrometry (AMS). The study has the goal of refining the precision and resolution of a segment of the conventional Bronze Age chronology in the Eurasian steppe attributed to the multicultural community known as Andronovo. The archaeological timbers were gathered from 3 cemeteries at the Lisakovsky cluster of sites in Kazakhstan, where there is a prominent Andronovo occurrence that appears to show evidence of overlapping Alakul and Fedorovo cultures in the southern margin of the Eurasian steppe. The new set of Andronovo calendar dates derived from 14C wiggles and a composite floating tree-ring chronology places the cultural overlap from 1780 to 1660 cal BC. Results indicate older ages of artifacts from the Lisakovsky site than were previously determined by the typological chronology, shifting them from the Late Bronze Age to also include the transition between the Middle and Late Bronze Age. The chronological order of the Lisakovsky cemeteries provides strong evidence of contemporaneity of the Alakul and Fedorovo cultures in the Tobol River Valley for a portion of the 120-yr period of occupation. We discuss an application of the dated Alakul-Fedorovo overlap to the relationship and origin of different groups of the Andronovo community in the Ural region. Our results demonstrate the substantial power that tree rings from Bronze Age timbers provide for developing a precise and highly resolved calendar chronology of prehistoric human occupation in the Eurasian steppe during the 2nd millennium BC.

Fischer and Heinemeier (2003) present a hypothesis that the freshwater reservoir effect produces old apparent ages for radiocarbon dates run on charred cooking residues in regions where fossil carbon is present in groundwater. The hypothesis is based in part on their analysis of dates on charred cooking residues from 3 inland archaeological sites in Denmark in relation to contextual dates from those sites on other materials. A critical assessment of the dates from these sites suggests that rather than a pattern of old apparent dates, there is a single outlying date—not sufficient evidence on which to build a case for the freshwater reservoir effect.

This report summarizes the radiocarbon dates obtained at the University of Wisconsin since November 1964; the procedures followed have been described previously (Wisconsin I, 1965).

The counting equipment has been supplemented with a second detector of 500 ml volume for which the nominal background at 1 std atm, 298.2° K, is 2.1 cpm as determined with petroleum methane (Phillips Petroleum Co.). The corresponding standard count for contemporary methane derived from NBS oxalic acid 95% Aox, is nominally 2.8 cpm at 1 std atm, 298.2° K. The additional counting equipment was also obtained from the Sharp Division of Beckman Instrument Co.

The Radiocarbon Dating Laboratory of the University of Texas was reorganized in late 1962. The dates reported in this list were obtained from February to November, 1963. The laboratory uses liquid scintillation counting with benzene solutions (Tamers, Stipp, and Collier, 1961; Noakes et al., 1963). The chemical synthesis has been modified and improved in several ways in order to permit one worker to produce a sample per day.

The radiocarbon content of dissolved organic carbon (DOC) in rivers, lakes, and other non-saline waters can provide valuable information on carbon cycling dynamics in the environment. DOC is typically prepared for 14C analysis by accelerator mass spectrometry (AMS) either by ultraviolet (UV) oxidation or by freeze-drying and sealed tube combustion. We present here a new method for the rapid analysis of 14C of DOC using wet chemical oxidation (WCO) and automated headspace sampling of CO2. The approach is an adaption of recently developed methods using aqueous persulfate oxidant to determine the δ13C of DOC in non-saline water samples and the 14C content of volatile organic acids. One advantage of the current method over UV oxidation is higher throughput: 22 samples and 10 processing standards can be prepared in one day and analyzed in a second day, allowing a full suite of 14C processing standards and blanks to be run in conjunction with samples. A second advantage is that there is less potential for cross-contamination between samples.

The dates reported in this list are for geologic and archaeologic samples only. During the interval since our last date list (R, 1966, v 8, p 498-506) most of our measurements have been on samples of sea water. These will be reported separately at a later time. The methods used are essentially those reported previously (R, 1963, v 5, p 80-81) but with the following notable changes and additions: We now prepare our methane counting gas as described in Buddemeier et al (1970). Our IL membrane counter has since been augmented by 3 additional counters. Two of these are IL quartz proportional counters inside geiger anticoincidence shields. Operating pressures are ca 1.5 to 4atm. Backgrounds of these 2 counters are in the neighborhood of 1.8 and 3cpm and the net counting rate of NBS oxalic acid ranges from 7 to 18.7cpm, depending on the pressure. The third counter (“minicounter”) is rather special: .IL quartz proportional counter inside a methane proportional anticoincidence counter. Sample and anticoincidence counting gases are introduced simultaneously with a differential pressure that never exceeds a few cm Hg. The sample filling side is constructed so as to minimize dead volume; over 80% of the sample gas is inside the active volume of the 14C counter. The range of filling pressures which are possible is ca 1 to 4atm.

This date list presents results of samples measured at ISOTOPES during 1968 and 1969 and several measurements made previously for which complete sample data has recently been received.

The results of a 10-year survey of 14C content in tree leaves from the vicinity of Swiss nuclear installations are reported. The interpretation is based on the results from a reference station showing a systematic decrease from δ14C = +350 in 1977 to ca 4–190 in 1987. Excess activities of up to ca 100 are observed in the vicinity of nuclear power plants which are compatible with release rates and dilution calculations. A higher excess of up to 1400 is measured in the close vicinity of a small research plant which releases the activity on top of the roof. The determined decrease of the activity with distance can be described by a power law with ca −1.4 in the exponent. Additional doses of 14C to plants and population from excess 14C activities are estimated to be negligible compared to natural doses.

Bronze Age human and animal bone collagen from several steppe Bronze Age cultures (i.e. Early Catacomb, East and West Manych Catacomb, and Lola cultures) shows large variations in δ13C and δ15N values. In general, we observed that the older the sample, the lower the δ13C and δ15N values. We hypothesize that more positive values of δ13C and δ15N are caused by change in diet and a more arid climate. For ancient sheep during drier periods of the Early Catacomb, East and West Manych Catacomb, and Lola cultures, we observed 2 groups with different C and N isotopic compositions, reflecting consumption of different types of fodder. During periods of aridization, C4 and C3 plants with high δ15N values appeared in the vegetation, also influencing bone collagen values. Human bones show reservoir effects, caused by aquatic diet components. These effects can be quantified by paired dating of human bone and associated terrestrial samples. Reservoir corrections have revised chronologies for the region. Some paired dates do not reveal reservoir effects. This can be explained in 2 alternative ways. One is that the human diet did not include aquatic components; rather, the diet was based on C3 vegetation with high δ15N values (13–15‰), and flesh/milk of domesticated animals. An alternative explanation is that humans consumed food from freshwater resources without reservoir effects.

Measurements of 14C activity as well as determinations of the stable isotope composition (18O, 2H and 13C) of groundwater samples were made to investigate the flow path, origin, recharge and age of the Botucatu Aquifer System in Brazil, between 1984 and 1987. The stable oxygen isotope composition reflects infiltration during several climatic recharge conditions. Measured 14C activities range from 0.4 to 94.2% modern. δ13C values enable us to distinguish two groundwater types of different origins. There is a gradual increase of 14C ages from the outcrop area towards the central part of the basin, associated with a progression of the confining conditions. Anomalous fluoride contents seem to be correlated with high 14C ages of the groundwater. The reliability of the 14C data is discussed.