The following is a list of radiocarbon dates obtained since the time of the preparation of Michigan list III.∗ The description of the essential features of our method of measurement as given in the introduction to list III applies to this list. The modern standards used were obtained from hardwood logs, and were of various ages from 75 to 150 years by ring count. These standards were sufficiently old so that no correction for the recent dilution of the atmospheric C14 is believed to be necessary in the dates reported here. The ages of carbonate sample are also calculated from modern wood as a reference standard, without any correction for isotope fractionation.

The following date list consists of samples prepared mainly during 1970 and 1971. Some old measurements, not included in previous lists are added. Ages reported here are calculated using the conventional half-life of 14C: 5568 years and NBS oxalic acid as recent standard.

The main purpose of this work is to reconstruct the atmospheric Δ 14C in the glacial-postglacial transition, 14,000 – 10,000 BP, a range not covered by the tree-ring calibration curve. We measured 14C/12C ratios on series of terrestrial macrofossils from sediments of two Swiss lakes. We selected exclusively plant remains of recognizable terrestrial origin that are not affected by hard water and thus reflect atmospheric 14C concentration. Due to the scarcity of such material, we used accelerator mass spectroscopy. Cores of two lakes were measured to eliminate local effects and to check the reproducibility of results. This required a reliable, 14C-independent correlation of the cores, obtained through local pollen zone boundaries 14C ages were obtained as a function of the depth in the cores. If sedimentation rates are known ages can be converted into Δ 14C values. We also attempted estimating sedimentation rates; calculations are based on the Swedish varve chronology. Results were combined to form an entire data set. The Δ 14C curve shows an increase with time during the Allerød and decreases during Preboreal and Bølling periods. Probabilities for these 14C variations are discussed.

Charcoal samples from ancient human occupation sites in Australia have been subjected to a rigorous pretreatment and stepped combustion regime in order to explore the possibility that these sites may be older than previous radiocarbon dating had suggested. In one case, the Devil's Lair site in southwest Australia, the methodology has clearly removed vestiges of contamination by more modern carbon and has led to a revised radiocarbon chronology that provides evidence for human occupation of southwest Australia by at least 44 ka BP and probably by 46–47 ka BP. In contrast, charcoal from the Nauwalabila site has been so severely altered that insufficient of the original carbon remains for reliable 14C dating. Finally, where the charcoal is well preserved, such as at the Carpenter's Gap site, the new results provide reassurance that earlier 14C results of ∼40 ka BP are indeed true ages and are not simply at the limit of the 14C technique.

We report on new 14C measurements of samples of 18 texts (scrolls) and 2 linen fragments from Qumran Caves 1, 2, and 4 and from Nahal Hever, both in the Dead Sea region. The radiocarbon results are in good agreement with estimates of age based on paleography.

Radiocarbon dating at the Tell el-Daba site in the Nile Delta has created an enigma for many years. Despite great efforts, the difference of about 120 yr between the chronology based on 14C dates and the one based on archaeological evidence linked to the Egyptian historical chronology has not been solved. In order to foster open discussions on this discrepancy, we present here the results of 40 14C accelerator mass spectrometry (AMS) measurements on short-lived plant material assigned to 14 different phases of the Tell el-Daba excavation, spanning 600 yr (about 2000–1400 BC). On the one hand, the recently established agreement between 14C dates and dynastic Egypt (Bronk Ramsey et al. 2010) makes it unlikely that the problem lies in the 14C dates and/or the Egyptian historical chronology. On the other hand, the extensive archaeological evidence from Tell el-Daba linked to many different cultures in the eastern Mediterranean and to the Egyptian historical chronology provides strong evidence for an absolute chronology shifted by about 120 yr with respect to the 14C dates.

We present for the first time a fully calibrated radiocarbon chronology of Proto-Neolithic and Neolithic cultures in the Middle East covering the time range from 12,500 to 5500 cal BC. A total of 1300 14C dates were evaluated, leading to the selection of 731 reliable dates. These were calibrated in a special collective approach presented in a series of graphs. The 14C dates are derived from 160 sites across the Middle East. The period with Proto-Neolithic cultures began around 12500 cal BC and lasted for more than 4000 years. The true Neolithic, with agriculture and livestock breeding, appeared just before 8000 cal BC, subsequently spreading across a wide area within just a few hundred years. Ceramics first occurred around 7000 cal BC. The Mesopotamian cultures that emerged around 6000 cal BC started the urban revolution.

Determined independently from annually laminated ice cores and lake sediments, and German pines, the calendar ages of Younger Dryas (YD) boundaries significantly disagree with one another. 14C dates, plotted vs. calendar ages for samples from different sediments, also reveal distinct offsets. The adjustment of varve chronologies to synchronize the boundaries of the YD nearly cancels the discrepancies between 14C data, and supports the synchronism of the YD cold period over the North Atlantic region. However, the exact timing of the event cannot be estimated in this way.

Databases of accumulated paleoecological and archaeological records provide a means for large-scale syntheses of environmental and cultural histories. We describe the current status of the Canadian Archaeological Radiocarbon Database (CARD), a searchable collection of more than 36,000 14C dates from archaeological and paleontological sites from across North America. CARD, built by the late Dr Richard Morlan of the Canadian Museum of Civilization, consists of uncalibrated 14C data as well as information about the material dated, the cultural association of the date (e.g. Paleoindian, Archaic, Woodland), and its geographic location. The database can be used to study questions relating to prehistoric demography, migrations, human vulnerability to environmental change, and human impact on the landscape, but biases relating to sampling intensity and taphonomy must first be accounted for. Currently, Canada and the northern United States are well represented in the database, while the southern United States is underrepresented. The frequency of 14C dates associated with archaeological sites increases through time from 15,000 cal yr BP until European contact, which likely reflects, among other factors, both the destruction of older cultural carbon due to erosion and dissolution and increasing population numbers through time. An exploratory analysis of the dates reveals their distribution in both time and space, and suggests that the database is sufficiently complete to enable quantitative analysis of general demographic trends.

The acid-base-acid (ABA) procedure is a common chemical pretreatment used on most organic matter samples. Although this pretreatment is straightforward, there is no consensus among labs about the optimum strength of the chemicals, or even the temperature, to be used for digestions. Comparisons between 14C results obtained by samples undergoing ABA against other wet oxidations, such as acid-base oxidation followed by stepped-combustion (ABOX-SC) or α-cellulose on wood, have sometimes suggested that ABA does not always remove all contaminating carbon. In addition, if not all ABA protocols are the same, could it be said that one procedure is better than others or comparable to wet-oxidation pretreatments, if rigorously applied? To determine whether 14C-free samples showed any fraction modern carbon (FmC) deviations due to pretreatment strategies, 3 experiments were carried out. The first compared 14C results for wood samples at or near the limit of 14C dating, pretreated with a standard ABA protocol used at UC Irvine's Keck Carbon Cycle Accelerator Mass Spectrometry (KCCAMS) facility, with those obtained from ABA- and ABOX-SC-prepared aliquots of the same samples performed at Australian National University (ANU) in 2001. The second experiment subjected wood samples, ranging from ∼12 ka BP to 14C-free, to 5 selected published ABA pretreatments. Third, we evaluated whether the ABA protocol needs a higher-strength final acid step (particularly important for removing CO2 absorption when samples are submerged in alkaline solutions). We are able to show that rigorous ABA treatments exist that can provide robust, reproducible results for many wood samples that are known to be >>50 ka BP, implying that a lack of control over the procedure's outcome might be sample-related, rather than due simply to inadequacies in the chemical pretreatment.

Radiocarbon (14C) measurements of foraminifera often provide the only absolute age constraints in marine sediments. However, they are often challenging as their reliability and accuracy can be compromised by reduced availability of adequate sample material. New analytical advances using the MIni CArbon DAting System (MICADAS) allow 14C dating of very small samples, circumventing size limitations inherent to conventional 14C measurements with accelerator mass spectrometry (AMS). Here we use foraminiferal samples and carbonate standard material to assess the reproducibility and precision of MICADAS 14C analyses, quantify contamination biases, and determine foraminiferal 14C blank levels. The reproducibility of conventional 14C ages for our planktic (benthic) foraminiferal samples from gas measurements is 200 (130) yr, and has good precision as illustrated by the agreement between both standards and their reference values as well as between small gas- and larger graphitized foraminiferal samples (within 100±60 yr). We observe a constant contamination bias and slightly higher 14C blanks for foraminifera than for carbonate reference materials, limiting gas (graphite) 14C age determinations for foraminifera from our study sites to ~38 (~42) kyr. Our findings underline the significance of MICADAS gas analyses for 14C on smaller-than-conventional sized foraminiferal samples for paleoclimate reconstructions and dating.

In situ radiocarbon inorganic production and retention pathways are distinct from those of the more commonly used traditional organic/atmospheric 14C. In addition, a growing number of laboratories are extracting in situ cosmogenic 14C from quartz, using a variety of analytical techniques. As such, a flexible yet internally consistent set of procedures for data reduction that recognizes the unique nature of the in situ14C system is essential for reliable comparison of results among laboratories. This article thus presents a brief data reduction framework that can accommodate differences in both AMS and laboratory analytical techniques.

Compound-specific radiocarbon analysis (CSRA) of benzene polycarboxylic acids (BPCAs) yields molecular-level, source-specific information necessary to constrain isotopic signatures of pyrogenic carbon. However, the purification of individual BPCAs requires a multistep procedure that typically results in only microgram quantities of the target analyte(s). Such small samples are highly susceptible to contamination by extraneous carbon, which needs to be minimized and carefully accounted for in order to yield accurate results. Here, we undertook comprehensive characterization and quantification of contamination associated with molecular radiocarbon (14C) BPCA analyses through systematic processing of multiple authentic standards with both fossil and modern 14C signatures at various concentrations. Using this approach, we precisely apportion the contribution of extraneous carbon with respect to the four implemented subprocedures. Assuming a constant source and quantity of extraneous carbon we correct and statistically evaluate uncertainties in resulting 14C data. Subsequently, we examine the results of triplicate analyses of reference materials representing four different environmental matrices (sediment, soil, aerosol, riverine natural organic matter) and apportion their BPCA sources in terms of carbon residues derived from biomass or fossil fuel combustion. This comprehensive approach to CSRA facilitates retrieval of robust 14C data, with application in environmental studies of the continuum of pyrogenic carbon.

The calibration of radiocarbon dates on marine materials involves a global marine calibration with regional corrections. Data from well-associated marine and terrestrial materials in archaeological artifacts from northern Chile indicated that the calibration is valid for the period ad 200–900 and suggest that coastal upwelling intensities during that period were similar to those of the early 20th century.

At Tell Sabi Abyad, Syria, we obtained a robust chronology for the 7th to early 6th millennium BC, the Late Neolithic. The chronology was obtained using a large set of radiocarbon dates, analyzed by Bayesian statistics. Cultural changes observed at ~6200 BC are coeval with the 8.2 ka climate event. The inhabitation remained continuous.

Currently, there is significant ongoing research into the temporal and spatial variability of marine radiocarbon reservoir effects (MREs) through quantification of ΔR values. In turn, MRE studies often use large changes in ΔR values as proxies for changes in ocean circulation. ΔR values are published in a variety of formats with variations in how the errors on these values are calculated, making it difficult to identify trends or to compare values, unless the method of calculating the ΔR is explicitly described or all of the data are made available in the publication. This paper demonstrates the large range in ΔR values (+34 to −122) that can be obtained from a single, secure archaeological context when using the multiple paired sample approach, despite the fact that the terrestrial entities were of statistically indistinguishable 14C ages, as were the marine samples. This demonstrates the inherent variability in the ΔR calculations themselves and we propose that, together with calculation of mean ΔR, the distribution of ΔR values should be displayed, e.g. as histograms in order to illustrate the full data range. This spread is only apparent when employing a multiple paired sample approach as the uncertainty derived on a single pair of samples, taking account only of the errors on the individual 14C ages, will never truly represent the overall variability in ΔR that results from the intrinsic variability in the population of 14C ages in samples that might have been used. Consequently, ΔR values and the associated uncertainty calculated from single pairs should be treated with some caution. We propose that, where possible, when using paired archaeological samples, that a multiple paired approach should be employed as it will test the context security of the material used in the ΔR calculations. When summarizing the values by the weighted average, we also propose that the standard error for predicted values should be employed as this will fully encompass the uncertainty of a future ΔR calculation, using different samples for a similar time and location. Finally, we encourage future publishing of ΔR values using the histogram format, making all of the data available. This will help ensure that ΔR values are comparable across the literature and should provide a framework for standardization of publication methods.

The 2-L counter (GSC I) and the 5-L counter (GSC IV) were operated routinely during the past year. The 5-L counter was operated at 1 atm, except for February-March 1967, when it was operated at 4 atm. Approximately half the determinations reported were obtained from each counter.

New Arizona high precision Δ14C data back to 6500 BC plot close to an 11,300-yr period sinusoid extrapolated from the post 5300 BC data (offset = +32‰, half amplitude = 51‰ and phase lag = 2.29 radians). The trend curve is modulated by high latitude components of the non-dipole field with a fundamental period of 2400 yr. Based upon a model of Lund and Banerjee (1985), the non-dipole field rotates and every 1200 yr the high latitude maxima pass over the north magnetic pole and near the south magnetic pole in reversed polarity. This modulates cosmic ray production producing extended maxima ca AD 1700, 700 bc, 3100 bc, and 5500 bc. The 2400 period appears to be stationary. The magnetic field also modulates the amplitude of the solar activity induced cycles of periods 200, 80, and 11 yr as can be seen in the Zürich-Bern Camp Century ice core data as well as in the Δ14 C fluctuation data. Reinterpretation of the Camp Century 10Be data indicates that it is in agreement with magnetic field as well as solar activity modulation of terrestrial radioisotope production.

The excavation of the Cyclope cave, situated on the deserted island of Youra in the Northern Sporades (39°22'N, 24°10'E), revealed material of marine and terrestrial origin in undisturbed layers, suitable for radiocarbon dating. In some cases, material from different reservoirs was found together in the same archaeological layer. This research had two aims. The first was the dating of charcoal-seashell pairs in order to determine the marine reservoir effect in this region, based on samples with ages spanning from the end of the 8th millennium to the beginning of the 7th millennium bc. The second aim was dating the stratigraphy of this site, by using the calculated δR value in conjunction with the marine calibration curve. This enabled the accurate calibration of the 14C ages of marine samples found in layers without charcoal pieces. The results show that this is the oldest human settlement ever found on an island in the Aegean Sea.

The new accelerator mass spectrometry (AMS) Radiocarbon Analysis Laboratory in Jena is described. The laboratory developed a combustion system for solid samples and a CO2 extraction system for air samples. Thus far, sample preparation, including graphitization, was performed in the laboratory, and the samples were measured subsequently by other AMS facilities. Currently, the laboratory owns a 3MV AMS system from HVEE (Netherlands) that has passed the acceptance tests and will be used for routine 14C determinations in the near future. The AMS system is equipped with 2 ion sources, one suitable for graphite targets and the second for both graphite and CO2 targets.