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On the “Lamellar” Morphology of Poly(p-Phenylene Terephthalamide) and Poly(p-Phenylene Benzobisthiazole)

Published online by Cambridge University Press:  26 February 2011

Eric J. Roche
Eric J. Roche*
Affiliation:
E.I. DuPont de Nemours & Co. Central Research and Development Department, Experimental Station, Box 80356, Wilmington DE 19880–0356, USA
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Abstract

Row-nucleated structures in PPTA and PBZT thin films are compared and their dependence upon quench rate and molecular weight illustrated. It is proposed that the lamellar appearance of the morphology is due to a coherent periodic twisting of fibrillar ribbons. The role of crystallosolvate phases is discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 134: Symposium J – Materials Science and Engineering of Rigid-Rod Polymers , 1988 , 457
Copyright
Copyright © Materials Research Society 1989

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References

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