Hostname: page-component-586b7cd67f-l7hp2 Total loading time: 0 Render date: 2024-11-29T07:57:39.397Z Has data issue: false hasContentIssue false

Preparation and Characterization of Sol-Gel Derived Heteroepitaxial LiNbO3 and LiTaO3 Thin Films

Published online by Cambridge University Press:  21 February 2011

Keiichi Nashimoto*
Affiliation:
Materials Research Laboratory, Fuji Xerox Co., Ltd., 1600 Takematsu, Minamiashigara, Kanagawa, 250-1, Japan
Get access

Abstract

Dense epitaxial LiNbO3 thin films without any misoriented plane on sapphire substrates were obtained with a sol-gel process utilizing 2-methoxyethanol based metal alkoxide precursors without pre-hydrolysis and rapid thermal annealing. Epitaxial LiNbO3 films annealed at 700°C were transparent and showed refractive indices close to bulk single crystal values. Epitaxial and transparent LiTaO3 films crystallized successfully on sapphire substrates with single orientations with the present process. X-ray rocking curve full widths at half maximum of epitaxial LiNbO3 and LiTaO3 films on sapphire (110) substrates and annealed at 700°C were less than 0.4 degree.

Type
Research Article
Copyright
Copyright © Materials Research Society 1993

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Adachi, H., Kawaguchi, T., Kitabatake, M., and Wasa, K., Jpn. J. Appl. Phys. 22, suppl. 22-2,11 (1983).CrossRefGoogle Scholar
2. Nashimoto, K., Fork, D. K., and Geballe, T. H., Appl. Phys. Lett. 60,1199 (1992).CrossRefGoogle Scholar
3. Keijser, M. de, Dormans, G. J., Cillessen, J. F., Leeuw, D. M. de, and Zandbergen, H. W., Appl. Phys. Lett. 58, 2636 (1991).CrossRefGoogle Scholar
4. Partlow, D. P. and Greggi, J., J. Mat. Res., 2, 595 (1987).Google Scholar
5. Hirano, S. and Kato, K., Adv. Ceram. Mat. 3,503 (1988).Google Scholar
6. Chen, C., Ryder, D. F. Jr., and Spurgeon, W. A., J. Am. Ceram. Soc. 72, 1495 (1989).CrossRefGoogle Scholar
7. Swartz, S. L., Melling, P. J., and Grant, C. S. in Optical Materials, edited by Poker, D. B. and Ortiz, C. (Mater. Res. Soc. Proc. 152, Pittsburgh, PA, 1989) pp. 227232.Google Scholar
8. Okuwada, K., Nakamura, S., Imai, M., and Kakuno, K., Jpn. J. Appl. Phys. 30, L1052 (1991).CrossRefGoogle Scholar
9. Nashimoto, K. and Cima, M. J., Mater. Lett. 10, 348 (1991).CrossRefGoogle Scholar
10. Nashimoto, K., Cima, M. J., and Rhine, W. E. in Ferroelectric Thin Films, edited by Bhalla, A. S. and Nair, K. M. (Am. Ceram. Soc. Ceram. Trans. 25, Westerville, OH, 1992) pp. 371383.Google Scholar
11. Eichost, D. J. and Payne, D. A. in Sol-Gel Optics, edited by Mackenzie, J. D. and Ulrich, D. R. (SPIE Proc. 1328, Bellingham, WA, 1990) pp. 456465.CrossRefGoogle Scholar
12. Hirano, S. and Kato, K. in Processing Science of Advanced Ceramics, edited by Aksay, I. A., McVay, G. L., and Ulrich, D. R. (Mater. Res. Soc. Proc. 155, Pittsburgh, PA, 1989) pp. 181190.Google Scholar