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Cadmium sulfide/lead sulfide co-sensitized TiO2 enhances photoelectrochemical performance and corrosion resistance of 304 stainless steel

Published online by Cambridge University Press:  19 November 2019

Xinhua Zheng Open the ORCID record for Xinhua Zheng [Opens in a new window] ,
Subhabrata Das ,
Yanhong Gu ,
Shikai Liu ,
James Borovilas  and
Jie Zhao Open the ORCID record for Jie Zhao [Opens in a new window]
Xinhua Zheng
Affiliation:
Beijing Key Laboratory of Pipeline Critical Technology and Equipment for Deepwater Oil & Gas Development, Beijing102617, China
Subhabrata Das
Affiliation:
Langmuir Center of Colloids and Interfaces, Columbia University in the City of New York, 500 W. 120th St, Mudd, New York, NY10027, USA
Yanhong Gu*
Affiliation:
Beijing Key Laboratory of Pipeline Critical Technology and Equipment for Deepwater Oil & Gas Development, Beijing102617, China
Shikai Liu
Affiliation:
School of Material Science and Engineering, Henan University of Technology, Zhengzhou450000, China
James Borovilas
Affiliation:
Program of Materials Science and Engineering, Department of Applied Physics and Applied Mathematics, Columbia University, New York, NY10027, USA
Jie Zhao
Affiliation:
Beijing Key Laboratory of Pipeline Critical Technology and Equipment for Deepwater Oil & Gas Development, Beijing102617, China
*
Address all correspondence to Yanhong Gu at [email protected], [email protected]
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Abstract

This paper proposes to improve the corrosion resistance of stainless steel using the photocathodic protection (PCP) method with CdS/PbS/titanium dioxide (TiO2) as the photoanode material. Cadmium sulfide (CdS)/lead sulfide (PbS) quantum dot (QD) heterostructure layered on TiO2 enhanced the photoelectrochemical performance and improved the PCP of 304 stainless steel. The photoanode film can protect 304 stainless steel for a period of upto 3 months against corrosion. This work demonstrates that CdS/PbS/TiO2 tandem heterostructure is a promising durable and stable photoanode, which can protect stainless steel in both dark and illuminated conditions.

Type
Research Letters
Information
MRS Communications , Volume 9 , Issue 4 , December 2019 , pp. 1361 - 1369
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Copyright
Copyright © Materials Research Society 2019

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