Hostname: page-component-586b7cd67f-t8hqh Total loading time: 0 Render date: 2024-11-23T16:08:45.509Z Has data issue: false hasContentIssue false

A New Method for Fast XRPD Using a Position Sensitive Detector

Published online by Cambridge University Press:  06 March 2019

Herbert E. Göbel*
Affiliation:
Forschungslaboratorien der SIEMENS AG D 8000 München 83, West Germany
Get access

Abstract

The scanning speed of powder diffractometers can be increased by about two orders of magnitude by replacing the normal detection system (receiving slit/scintillation counter) by a linear position sensitive detector (PSD) which collects diffracted x-rays of a larger part of the diffractometer measuring arc simultaneously. The velocity increase is proportional to the section of the arc 29 in which the diffracted x-rays are detected. With respect to the Bragg-Brentano focussing geometry, a range of several degrees (typically 5°) can be tolerated without affecting the resolution remarkably. Diffractograms over extended angular regions of 2θ are received by slewing the PSD continuously along the arc while the diffracted x-rays are accumulated with their accurate 2θ angle address on a digital base.

The method has been named the continuous position sensitive detection technique (CPSD). With this technique, diffraction patterns with similar quality (resolution, linearity, peak/background ratio) as conventional, scintillation counter recorded diagrams can be received at slewing rates of several hundred degrees per minute. Additionally, the CPSD technique augments the number of crystallites contributing to the diffraction intensity by the same amount, thus producing much better crystallite statistics for quantitative measurements.

Type
Research Article
Copyright
Copyright © International Centre for Diffraction Data 1978

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

(1) Sparks, R. A., et al., U.S. Patent 4,076,981, Feb. 28, 1978; and Advances in X-Ray Analysis, Vol. 20.Google Scholar
(2) Brentano, J. C. M., Proc. Phys. Soc. 49, 6177 (1936).Google Scholar
(3) Manufactured by Braun, M. Co., Munich. The PSPC and the associated electronics are part of the SIEMENS analytical equipment programme.Google Scholar
(4) Borkowski, C. J., Kopp, M. K., Rev. Sci. Instrum. 38, 1515-1522, (1968).Google Scholar
(5) ORTEC 457 biased time to pulse height converter.Google Scholar
(6) Parrish, W., Huang, T. C., Ayers, G. L., Paper 144-13, XI. Int. Congress of Crystallography, Warszawa, Poland, Aug. 312 (1978).Google Scholar