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Some Studies of Chlorinated Poly(Vinyl Chloride) Using X-Ray Photoelectron Spectroscopy

Published online by Cambridge University Press:  06 March 2019

James Gianelos
Affiliation:
The BFGoodrich Research & Development Center Brecksville, Ohio 44141
Eric A. Grulke
Affiliation:
The BFGoodrich Research & Development Center Brecksville, Ohio 44141
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Extract

Chlorinated poly(vinyl chloride) (CPVC) is similar in many ways to its thermoplastic parent poly(vinyl chloride) (PVC), Chlorination imparts superior high temperature properties, which make CPVC preferable for many and varied applications.

Our primary purpose in studying CPVC with x-ray photoelectron spectroscopy (XPS) was to see whether we could gain insight into how chlorine substitutes into the PVC molecule. We also hoped we would obtain insights into the chlorination reaction itself, and how variations would affect the final product.

Type
Research Article
Copyright
Copyright © International Centre for Diffraction Data 1978

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References

1. Swingle, R. S. II, “Quantitative Surface Analysis by X-Ray Photoelectron Spectroscopy (ESCA),” Analytical Chemistry 47, 2124 (1975).Google Scholar